4-氯异丙苯
化合物
4-氯异丙苯是一种有机氯化合物，化学式为C9H11Cl。它可由异丙苯和氯气在乙酸中，或和次氯酸叔丁酯在沸石存在下于乙腈中反应制得，该反应会产生少量的2-氯异丙苯。[2]在氯化亚铁催化下，它可以被过氧化氢氧化为4'-氯苯乙酮。[3]
| 4-氯异丙苯 | |
|---|---|
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| 识别 | |
| CAS号 | 2621-46-7 
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| SMILES |
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| 性质 | |
| 化学式 | C9H11Cl |
| 摩尔质量 | 154.64 g·mol−1 |
| 熔点 | −12.3 °C[1] |
| 沸点 | 198.3 °C[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2024-07-02].
- ^ Smith, Keith; Butters, Michael; Nay, Barry. Highly para-Selective Mono-Chlorination of Aromatic Compounds Under Mild Conditions by t-Butyl Hypochlorite in the Presence of Zeolites. Synthesis, 1985 (12), 1157–1158. doi:10.1055/s-1985-31462
- ^ Ning Xu, Lulu Zhou, Linlin Zhao, Mengying Guo, Linlin Yang, Wei Han. Iron-Catalyzed Oxidative C−C Bond Cleavage of Unstrained Tertiary Alkyl Aromatics to Arylketones. Advanced Synthesis & Catalysis. 2023. 365 (15). doi:10.1002/adsc.202300410.