Well-Defined Chiral Gold(III) Complex Catalyzed Direct Enantioconvergent Kinetic Resolution of 1,5-Enynes (Q46126672)

19 December 2017

title

Well-Defined Chiral Gold(III) Complex Catalyzed Direct Enantioconvergent Kinetic Resolution of 1,5-Enynes (English)

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19 December 2017

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2

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19 December 2017

author name string

Patrick T Bohan

series ordinal

1

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19 December 2017

language of work or name

English

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publication date

3 August 2017

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19 December 2017

number of pages

4

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Journal of the American Chemical Society

inferred from page(s)

published in

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19 December 2017

volume

139

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19 December 2017

issue

32

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19 December 2017

page(s)

11016-11019

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19 December 2017

C,O-Chelated BINOL/Gold(III) Complexes: Synthesis and Catalysis with Tunable Product Profiles.

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Gold-Catalyzed Enantioselective Annulations

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Fluorine and Gold: A Fruitful Partnership

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Metal-catalyzed cycloisomerization as a powerful tool in the synthesis of complex sesquiterpenoids.

3 November 2018

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Gold carbenes, gold-stabilized carbocations, and cationic intermediates relevant to gold-catalysed enyne cycloaddition.

3 November 2018

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Recent advances in enantioselective gold catalysis

3 November 2018

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Reactivity of Gold Complexes towards Elementary Organometallic Reactions.

3 November 2018

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Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity.

3 November 2018

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Stable gold(III) catalysts by oxidative addition of a carbon-carbon bond

3 November 2018

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Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors

3 November 2018

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Molecular complexity from polyunsaturated substrates: the gold catalysis approach

3 November 2018

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Exceptionally fast carbon-carbon bond reductive elimination from gold(III).

3 November 2018

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Development of catalysts and ligands for enantioselective gold catalysis

3 November 2018

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Gold-catalyzed rearrangements and beyond

3 November 2018

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NHC-capped cyclodextrins (ICyDs): insulated metal complexes, commutable multicoordination sphere, and cavity-dependent catalysis

3 November 2018

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One-point binding ligands for asymmetric gold catalysis: phosphoramidites with a TADDOL-related but acyclic backbone

3 November 2018

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Chirality transfer and memory of chirality in gold-catalyzed reactions

3 November 2018

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Enantioselective, transition metal catalyzed cycloisomerizations.

3 November 2018

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Enantioselective cyclizations of silyloxyenynes catalyzed by cationic metal phosphine complexes

3 November 2018

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Chiral (acyclic diaminocarbene)gold(I)-catalyzed dynamic kinetic asymmetric transformation of propargyl esters

3 November 2018

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Enantioconvergent Hydroboration of a Racemic Allene: Enantioselective Synthesis of (E)-δ-Stannyl-anti-homoallylic Alcohols via Aldehyde Crotylboration

3 November 2018

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An Enyne Cycloisomerization Approach to the Triple Reuptake Inhibitor GSK1360707F

3 November 2018

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Asymmetric Suzuki cross-couplings of activated secondary alkyl electrophiles: arylations of racemic alpha-chloroamides

3 November 2018

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Gold(I)-catalyzed enantioselective polycyclization reactions

3 November 2018

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Asymmetric Au(i)-catalyzed synthesis of bicyclo[4.1.0]heptene derivatives via a cycloisomerization process of 1,6-enynes

3 November 2018

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Cycloisomerization of 1,n-enynes: challenging metal-catalyzed rearrangements and mechanistic insights.

3 November 2018

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Gold(III) Salen complex-catalyzed synthesis of propargylamines via a three-component coupling reaction

3 November 2018

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Efficiency in nonenzymatic kinetic resolution.

3 November 2018

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Catalytic isomerization of 1,5-enynes to bicyclo[3.1.0]hexenes

3 November 2018

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Platinum- and gold-catalyzed cycloisomerization reactions of hydroxylated enynes

3 November 2018

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Organometallic gold(III) compounds as catalysts for the addition of water and methanol to terminal alkynes.

3 November 2018

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PtCl2-catalyzed cycloisomerizations of 5-en-1-yn-3-ol systems

3 November 2018

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12 December 2020

Enantioselective alkynylbenzaldehyde cyclizations catalyzed by chiral gold(I) acyclic diaminocarbene complexes containing weak Au-arene interactions

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12 December 2020

Helicenes with embedded phosphole units in enantioselective gold catalysis

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12 December 2020

Oxidative addition of carbon-carbon bonds to gold

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12 December 2020

Direct enantio-convergent transformation of racemic substrates without racemization or symmetrization

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12 December 2020

Transition metal catalyzed cycloisomerizations of 1,n-allenynes and -allenenes

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12 December 2020

Gold catalysis: the benefits of N and N,O ligands

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12 December 2020

Identifiers

DOI

10.1021/JACS.7B06025

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19 December 2017

PMC publication ID

5911161

0 references

1 reference

19 December 2017