Ligand-accelerated C-H activation reactions: evidence for a switch of mechanism (Q42161197)

17 October 2017

Ligand-accelerated C-H activation reactions: evidence for a switch of mechanism (English)

1 reference

17 October 2017

Dong-Hui Wang

2

0 references

Keary M Engle

object named as

Keary M Engle

series ordinal

1

0 references

author name string

Jin-Quan Yu

series ordinal

3

1 reference

PMC publication ID

2952432

17 October 2017

language of work or name

English

0 references

publication date

1 October 2010

1 reference

Journal of the American Chemical Society

17 October 2017

1 reference

17 October 2017

132

1 reference

17 October 2017

40

1 reference

17 October 2017

14137-14151

1 reference

Stable mononuclear organometallic Pd(III) complexes and their C-C bond formation reactivity

17 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2952432

Cationic Pd(II)-catalyzed Fujiwara-Moritani reactions at room temperature in water

26 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2952432

Pd(II)-catalyzed hydroxyl-directed C-H olefination enabled by monoprotected amino acid ligands

26 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2952432

Cationic palladium(II) catalysis: C-H activation/Suzuki-Miyaura couplings at room temperature

26 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2952432

Pd(II)-catalyzed olefination of sp3 C-H bonds

26 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2952432

Auxiliary-assisted palladium-catalyzed arylation and alkylation of sp2 and sp3 carbon-hydrogen bonds

26 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2952432

Organopalladium(IV) chemistry

26 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2952432

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

26 October 2017

1 reference

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Pd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acids

26 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2952432

Transition-metal-catalyzed direct arylation of (hetero)arenes by C-H bond cleavage.

26 October 2017

1 reference

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Ligand-enabled reactivity and selectivity in a synthetically versatile aryl C-H olefination

26 October 2017

1 reference

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Formation of ArF from LPdAr(F): catalytic conversion of aryl triflates to aryl fluorides

26 October 2017

1 reference

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Palladium(II)-catalyzed ortho alkylation of benzoic acids with alkyl halides

26 October 2017

1 reference

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Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality

26 October 2017

1 reference

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Palladium- and copper-catalyzed arylation of carbon-hydrogen bonds

26 October 2017

1 reference

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Versatile Pd(OTf)2 x 2 H2O-catalyzed ortho-fluorination using NMP as a promoter

26 October 2017

1 reference

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Pd(II)-catalyzed olefination of electron-deficient arenes using 2,6-dialkylpyridine ligands

26 October 2017

1 reference

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Versatile Pd(II)-catalyzed C-H activation/aryl-aryl coupling of benzoic and phenyl acetic acids

26 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2952432

Palladium-catalyzed cross-coupling reactions of organosilanols and their salts: practical alternatives to boron- and tin-based methods

26 October 2017

1 reference

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Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides

26 October 2017

1 reference

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Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

26 October 2017

1 reference

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Direct transition metal-catalyzed functionalization of heteroaromatic compounds

26 October 2017

1 reference

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Direct palladium-catalyzed alkynylation of N-fused heterocycles

26 October 2017

1 reference

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Sigma-chelation-directed C-H functionalizations using Pd(II) and Cu(II) catalysts: regioselectivity, stereoselectivity and catalytic turnover

26 October 2017

1 reference

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Aryl-aryl bond formation by transition-metal-catalyzed direct arylation.

26 October 2017

1 reference

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Direct Palladium-CatalyzedOrtho-Arylation of Benzylamines

26 October 2017

1 reference

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Catalytic intermolecular direct arylation of perfluorobenzenes.

26 October 2017

1 reference

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Palladium-catalyzed cross-coupling reactions in total synthesis

26 October 2017

1 reference

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The renaissance of palladium(II)-catalyzed oxidation chemistry

26 October 2017

1 reference

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Palladium oxidase catalysis: selective oxidation of organic chemicals by direct dioxygen-coupled turnover

26 October 2017

1 reference

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Palladium-catalyzed coupling reactions of aryl chlorides

26 October 2017

1 reference

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The atom economy--a search for synthetic efficiency

26 October 2017

1 reference

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Synthetic and mechanistic studies of Pd-catalyzed C-H arylation with diaryliodonium salts: evidence for a bimetallic high oxidation state Pd intermediate

26 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2952432

Distinct reactivity of Pd(OTs)2: the intermolecular Pd(II)-catalyzed 1,2-carboamination of dienes

29 May 2018

1 reference

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A short synthetic route to ( )-austamide, ( )-deoxyisoaustamide, and ( )-hydratoaustamide from a common precursor by a novel palladium-mediated indole --> dihydroindoloazocine cyclization

29 May 2018

1 reference

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Bimetallic palladium catalysis: direct observation of Pd(III)-Pd(III) intermediates

29 May 2018

1 reference

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Pd(II)-catalyzed amination of C-H bonds using single-electron or two-electron oxidants.

17 August 2018

1 reference

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Indoles from simple anilines and alkynes: palladium-catalyzed C-H activation using dioxygen as the oxidant.

17 August 2018

1 reference

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Total synthesis of ( /-)-rhazinal using novel palladium-catalyzed cyclizations

17 August 2018

1 reference

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The norbornene shuttle: multicomponent domino synthesis of tetrasubstituted helical alkenes through multiple C--H functionalization

17 August 2018

1 reference

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Oxidative Pd(II)-catalyzed C-H bond amination to carbazole at ambient temperature

17 August 2018

1 reference

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Synthesis of beta-, gamma-, and delta-lactams via Pd(II)-catalyzed C-H activation reactions

17 August 2018

1 reference

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Synthesis of indolines and tetrahydroisoquinolines from arylethylamines by Pd(II)-catalyzed C-H activation reactions

17 August 2018

1 reference

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Pd(II)-catalyzed cross-coupling of sp3 C-H Bonds with sp2 and sp3 boronic acids using air as the oxidant

17 August 2018

1 reference

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Regioselective C-H functionalization directed by a removable carboxyl group: palladium-catalyzed vinylation at the unusual position of indole and related heteroaromatic rings

17 August 2018

1 reference

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Palladium-catalyzed direct arylation of (hetero)arenes with aryl boronic acids

17 August 2018

1 reference

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A convergent synthesis of polysubstituted aromatic nitriles via palladium-catalyzed C-H functionalization.

17 August 2018

1 reference

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Indirect ortho functionalization of substituted toluenes through ortho olefination of N,N-dimethylbenzylamines tuned by the acidity of reaction conditions

17 August 2018

1 reference

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Ortho arylation of acetanilides via Pd(II)-catalyzed C-H functionalization

17 August 2018

1 reference

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Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation.

17 August 2018

1 reference

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Catalytic direct arylation with aryl chlorides, bromides, and iodides: intramolecular studies leading to new intermolecular reactions

17 August 2018

1 reference

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Palladium-catalyzed alkylation of aryl C-H bonds with sp3 organotin reagents using benzoquinone as a crucial promoter

17 August 2018

1 reference

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Computational study of the mechanism of cyclometalation by palladium acetate

17 August 2018

1 reference

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Highly regioselective arylation of sp3 C-H bonds catalyzed by palladium acetate

17 August 2018

1 reference

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Direct palladium-catalyzed C-2 and C-3 arylation of indoles: a mechanistic rationale for regioselectivity

17 August 2018

1 reference

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Cyclocarbopalladation involving an unusual 1,5-palladium vinyl to aryl shift as termination step: theoretical study of the mechanism.

17 August 2018

1 reference

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Directed palladation: fine tuning permits the catalytic 2-alkenylation of indoles

17 August 2018

1 reference

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17 August 2018

1 reference

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The total synthesis of ( )-dragmacidin F.

17 August 2018

1 reference

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Palladium-catalyzed oxygenation of unactivated sp3 C-H bonds

17 August 2018

1 reference

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Highly efficient and enantioselective cyclization of aromatic imines via directed C-H bond activation

17 August 2018

1 reference

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A highly selective catalytic method for the oxidative functionalization of C-H bonds

17 August 2018

1 reference

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The asymmetric intramolecular Heck reaction in natural product total synthesis

17 August 2018

1 reference

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Catalytic C-H bond functionalization with palladiumII: aerobic oxidative annulations of indoles

17 August 2018

1 reference

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Direct coupling of benzene with olefin catalyzed by Pd(OAc)(2) combined with heteropolyoxometalate under dioxygen

17 August 2018

1 reference

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Selective Pd-catalyzed oxidative coupling of anilides with olefins through C-H bond activation at room temperature

17 August 2018

1 reference

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Ru-catalyzed oxidative coupling of arenes with olefins using O(2).

17 August 2018

1 reference

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The Catalytic Alkylation of Aromatic Imines by Wilkinson's Complex: The Domino Reaction of Hydroacylation and ortho-Alkylation This work was supported by the Brain Korea 21 Project, the Yonsei University Faculty Research Grant (1999), and the KOSEF (

17 August 2018

1 reference

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A Simple Catalytic Method for the Regioselective Halogenation of Arenes

3 November 2018

1 reference

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Palladium-Catalyzed Fluorination of Carbon−Hydrogen Bonds

1 December 2018

1 reference

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Room Temperature Palladium-Catalyzed 2-Arylation of Indoles

1 December 2018

1 reference

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Oxidative C−H Activation/C−C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights

1 December 2018

1 reference

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Efficient activation of aromatic C-H bonds for addition to C-C multiple bonds

1 December 2018

1 reference

12 December 2020

Unusual Palladium-Catalyzed Cascade Arylation of alpha,beta-Unsaturated Phenyl Sulfones under Heck Reaction Conditions Financial support for this work by the Ministerio de Educación y Cultura (DGES, project PB96-0021), Ministerio de Ciencia y Tecnol

1 reference

12 December 2020

Fluoride-free cross-coupling of organosilanols

1 reference

12 December 2020

Catalytic functionalization of arenes and alkanes via C-H bond activation

1 reference

12 December 2020

The B-Alkyl Suzuki-Miyaura Cross-Coupling Reaction: Development, Mechanistic Study, and Applications in Natural Product Synthesis A list of abbreviations can be found at the end of the article

1 reference

12 December 2020

Toward waste-free production of Heck products with a catalytic palladium system under oxygen

1 reference

12 December 2020

Palladium-catalyzed asymmetric iodination of unactivated C-H bonds under mild conditions

1 reference

12 December 2020

Catalytic coupling of haloolefins with anilides

1 reference

12 December 2020

Palladium-catalyzed intermolecular alkenylation of indoles by solvent-controlled regioselective C-H functionalization

1 reference

12 December 2020

Catalytic coupling of C-H and C-I bonds using pyridine as a directing group

1 reference

12 December 2020

Combined C-H functionalization/C-N bond formation route to carbazoles

1 reference

12 December 2020

Pd-catalyzed stereoselective oxidation of methyl groups by inexpensive oxidants under mild conditions: a dual role for carboxylic anhydrides in catalytic C--H bond oxidation

1 reference

12 December 2020

Novel acetoxylation and C-C coupling reactions at unactivated positions in alpha-amino acid derivatives

1 reference

12 December 2020

Palladium-catalyzed alkylation of sp2 and sp3 C-H bonds with methylboroxine and alkylboronic acids: two distinct C-H activation pathways

1 reference

12 December 2020

Synthesis of 3-(diarylmethylenyl)oxindole by a palladium-catalyzed domino carbopalladation/C-H activation/C-C bond-forming process

1 reference

12 December 2020

High yield syntheses of stable, singly bonded Pd2(6 ) compounds

1 reference

12 December 2020

The first total synthesis of the peptaibol hypomurocin A1 and its conformation analysis: an application of the 'azirine/oxazolone method'

1 reference

12 December 2020

Palladium-Catalyzed Methylation and Arylation of sp2and sp3C−H Bonds in Simple Carboxylic Acids

1 reference

12 December 2020

Proton-abstraction mechanism in the palladium-catalyzed intramolecular arylation: substituent effects

1 reference

12 December 2020

Synthesis of rhazinicine by a metal-catalyzed C-H bond functionalization strategy

1 reference

12 December 2020

Pd(II)-catalyzed enantioselective activation of C(sp2)-H and C(sp3)-H bonds using monoprotected amino acids as chiral ligands

1 reference

12 December 2020

Pd(II)-catalyzed monoselective ortho halogenation of C-H bonds assisted by counter cations: a complementary method to directed ortho lithiation

1 reference

12 December 2020

Palladium-catalyzed C-H functionalization of pyridine N-oxides: highly selective alkenylation and direct arylation with unactivated arenes

1 reference

12 December 2020

Analysis of the concerted metalation-deprotonation mechanism in palladium-catalyzed direct arylation across a broad range of aromatic substrates

1 reference

12 December 2020

Intermolecular hydroarylation of unactivated olefins catalyzed by homogeneous platinum complexes

1 reference

12 December 2020

Palladium-catalyzed C-H bond functionalization with arylsulfonyl chlorides

1 reference

12 December 2020

Synthesis of condensed heteroaromatic compounds by palladium-catalyzed oxidative coupling of heteroarene carboxylic acids with alkynes

1 reference

12 December 2020

Palladium-catalyzed direct alkynylation of C-H bonds in benzenes

1 reference

12 December 2020

Palladium(II)-catalyzed regioselective direct C2 alkenylation of indoles and pyrroles assisted by the N-(2-pyridyl)sulfonyl protecting group

1 reference

12 December 2020

Emergence of palladium(IV) chemistry in synthesis and catalysis

1 reference

12 December 2020

Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation

1 reference

12 December 2020

Aromatic substitution of olefins. VI. Arylation of olefins with palladium(II) acetate

1 reference

12 December 2020

Identifiers

DOI

10.1021/JA105044S

1 reference

17 October 2017

1 reference

PMC publication ID

2952432

17 October 2017

PubMed publication ID

20853838

1 reference

PMC publication ID

2952432