Stable cyclic carbenes and related species beyond diaminocarbenes (Q37788080)

23 August 2017

Stable cyclic carbenes and related species beyond diaminocarbenes (English)

1 reference

23 August 2017

3

Guy Bertrand

1 reference

23 August 2017

1

Mohand Melaimi

1 reference

23 August 2017

Michèle Soleilhavoup

2

1 reference

PMC publication ID

3130005

23 August 2017

language of work or name

English

0 references

publication date

1 November 2010

1 reference

Angewandte Chemie International Edition

23 August 2017

0 references

volume

49

1 reference

23 August 2017

47

1 reference

23 August 2017

8810-8849

1 reference

Alkene oligomerisation and polymerisation with metal-NHC based catalysts

23 August 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Fused polycyclic nucleophilic carbenes - synthesis, structure, and function

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Metal-NHC complexes: a survey of anti-cancer properties.

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Asymmetric hydrogenation, transfer hydrogenation and hydrosilylation of ketones catalyzed by iron complexes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Metathesis in the synthesis of aromatic compounds.

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Ruthenium Vinyl Carbene Intermediates in Enyne Metathesis

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

The medicinal applications of imidazolium carbene-metal complexes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Mechanistic surprises in the gold(I)-catalyzed intramolecular hydroarylation of allenes.

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Ruthenium-based olefin metathesis catalysts bearing N-heterocyclic carbene ligands

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Cyclic (Alkyl)(amino)carbene Gold(I) complexes: A Synthetic and Structural Investigation.

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Selective monoarylation of acetate esters and aryl methyl ketones using aryl chlorides

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

13C NMR spectroscopy of "Arduengo-type" carbenes and their derivatives

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal Complexes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

An improved protocol for the Pd-catalyzed alpha-arylation of aldehydes with aryl halides.

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Well-defined N-heterocyclic carbenes-palladium(II) precatalysts for cross-coupling reactions

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Broader, greener, and more efficient: recent advances in asymmetric transfer hydrogenation.

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Hydroamination: direct addition of amines to alkenes and alkynes.

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

N-Heterocyclic carbene complexes of rhodium: structure, stability and reactivity

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Development of palladium-carbene catalysts for telomerization and dimerization of 1,3-dienes: from basic research to industrial applications

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Ligand effects in homogeneous Au catalysis

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Alternative synthetic methods through new developments in catalysis by gold

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Gold-Catalyzed Organic Transformations

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Coinage metal-assisted synthesis of heterocycles.

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Tuning the nucleophilicity in cyclopropenylidenes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Heterocyclic carbenes: synthesis and coordination chemistry.

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Anionic tethered N-heterocyclic carbene chemistry

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Asymmetric hydroamination of non-activated carbon-carbon multiple bonds.

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Organocatalysis by N-heterocyclic carbenes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Recently reported crystalline isothiazole carbenes: myth or reality

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

The catalytic hydroamination of alkynes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Synthesis of phosphaformamidines and phosphaformamidinates

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Chemical routes for the transformation of biomass into chemicals

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Stable P-heterocyclic carbenes: scope and limitations.

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Catalytic carbophilic activation: catalysis by platinum and gold pi acids

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions--a synthetic chemist's perspective

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Stable four-pi-electron, four-membered heterocyclic cations and carbenes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Mechanistic aspects of transition metal-catalyzed hydrogen transfer reactions.

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Asymmetric transfer hydrogenation: chiral ligands and applications

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Scope and mechanistic study of the ruthenium-catalyzed ortho-C-H bond activation and cyclization reactions of arylamines with terminal alkynes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Proton-catalyzed hydroamination and hydroarylation reactions of anilines and alkenes: a dramatic effect of counteranions on reaction efficiency

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Stable planar six-pi-electron six-membered N-heterocyclic carbenes with tunable electronic properties

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Efficient C-F and C-C activation by a novel N-heterocyclic carbene-nickel(0) complex

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Diaminocarbene- and Fischer-carbene complexes of palladium and nickel by oxidative insertion: preparation, structure, and catalytic activity

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

New C-N and C-C bond forming reactions catalyzed by titanium complexes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Bis(diethylamino)carbene and the mechanism of dimerisation for simple diaminocarbenes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

When and how do diaminocarbenes dimerize?

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Catalytic Markovnikov and anti-Markovnikov functionalization of alkenes and alkynes: recent developments and trends

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Evidence for specific solvation of two halocarbene amides

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Palladium-Catalyzed α-Arylation of Carbonyl Compounds and Nitriles

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

(Amino)(Aryl)Carbenes: Stable Singlet Carbenes Featuring a Spectator Substituent

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

The development of L2X2Ru=CHR olefin metathesis catalysts: an organometallic success story

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Synthesis and activity of a new generation of ruthenium-based olefin metathesis catalysts coordinated with 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ligands

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium salts

14 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap.

14 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes

14 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Abnormal ligand binding and reversible ring hydrogenation in the reaction of imidazolium salts with IrH(5)(PPh(3))(2).

14 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis, Structure, and Catalytic Activity

14 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

A New Synthetic Method for the Preparation of Protonated-NHCs and Related Compounds

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs).

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Palladium complexes of abnormal N-heterocyclic carbenes as precatalysts for the much preferred Cu-free and amine-free Sonogashira coupling in air in a mixed-aqueous medium

23 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines

23 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

A cationic gold(I) complex as a general catalyst for the intermolecular hydroamination of alkynes: application to the one-pot synthesis of allenes from two alkynes and a sacrificial amine

23 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Homogeneous catalytic hydroamination of alkynes and allenes with ammonia

23 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

A methylene-bis-triazolium ligand precursor in an unusual rearrangement of norbornadiene to nortricyclyl

23 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Coordination chemistry at carbon

23 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Atropochiral (C,C)-chelating NHC-ylide ligands: synthesis and resolution of palladium(II) complexes thereof.

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

N-heterocyclic carbenes bearing two, one and no nitrogen atoms at the ylidene carbon: insight from theoretical calculations

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Syntheses and X-ray crystal structures of cationic, two-coordinate gold(I) pi-alkene complexes that contain a sterically hindered o-biphenylphosphine ligand

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Synchrotron photoionization measurements of combustion intermediates: photoionization efficiency and identification of C3H2 isomers

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Synthesis and structural characterisation of stable cationic gold(I) alkene complexes.

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Exocyclic delocalization at the expense of aromaticity in 3,5-bis(pi-donor) substituted pyrazolium ions and corresponding cyclic bent allenes.

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Nonmetal-mediated fragmentation of P4: isolation of P1 and P2 bis(carbene) adducts.

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Synthesis and ligand properties of a persistent, all-carbon four-membered-ring allene

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivatives

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Theoretical analysis of bonding in N-heterocyclic carbene-rhodium complexes.

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Beyond conventional N-heterocyclic carbenes: abnormal, remote, and other classes of NHC ligands with reduced heteroatom stabilization

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Divalent silicon(0) compounds

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Ion pairing in cationic olefin-gold(I) complexes

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

N-Heterocyclic carbenes/imidazolium salts as substrates in catalysis: the catalytic 2-substitution and annulation of heterocyclic compounds.

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Stable five-membered-ring allenes with second-row elements only: not allenes, but zwitterions

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Isolation of bicyclopropenylidenes: derivatives of the smallest member of the fulvalene family

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

[IrCl(2)Cp*(NHC)] complexes as highly versatile efficient catalysts for the cross-coupling of alcohols and amines

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Palladation of diimidazolium salts at the C4 position: access to remarkably electron-rich palladium(II) centers

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

A persistent P,N-heterocyclic carbene.

1 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3130005

Topological and orbital-based mechanisms of the electronic stabilization of bis(diisopropylamino)cyclopropenylidene

1 September 2018

1 reference

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Synthesis and ligand properties of stable five-membered-ring allenes containing only second-row elements

1 September 2018

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Diaminocarbene and phosphonium ylide ligands: a systematic comparison of their donor character.

1 September 2018

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Cyclic (amino)[bis(ylide)]carbene as an anionic bidentate ligand for transition-metal complexes

1 September 2018

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A highly efficient and selective Au(I)-catalyzed tandem synthesis of diversely substituted pyrrolo[1,2-a]quinolines in aqueous media.

1 September 2018

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Divalent carbon(0) chemistry, part 1: Parent compounds.

1 September 2018

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Synthesis of an extremely bent acyclic allene (a "carbodicarbene"): a strong donor ligand

1 September 2018

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Five-membered metallacyclic allenoids: synthesis and structure of remarkably stable strongly distorted cyclic allene derivatives

1 September 2018

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The existence of two short-bond isomers for bicyclo[1.1.0]butane derivatives based on boron and phosphorus

1 September 2018

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Organocatalytic ring-opening polymerization.

1 September 2018

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NHC-mediated aggregation of P4: isolation of a P12 cluster

1 September 2018

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Bonding analysis of N-heterocyclic carbene tautomers and phosphine ligands in transition-metal complexes: a theoretical study

1 September 2018

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Mechanism of the electronic stabilization of the 3MR and divalent carbon of bis(diisopropylamino)cyclopropenylidene

1 September 2018

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Carbene activation of P4 and subsequent derivatization

1 September 2018

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Cyclopropenylidene carbene ligands in palladium C-C coupling catalysis.

1 September 2018

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Alkene metathesis: the search for better catalysts.

1 September 2018

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Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center.

1 September 2018

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Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs).

1 September 2018

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Cyclic carbodiphosphorane-diphosphinocarbene thermal interconversion.

1 September 2018

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Pyrazolidine-3,5-diones and 5-hydroxy-1H-pyrazol-3(2H)-ones, inhibitors of UDP-N-acetylenolpyruvyl glucosamine reductase.

1 September 2018

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Isolation of cyclopropenylidene-lithium adducts: the Weiss-Yoshida reagent

1 September 2018

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Strain estimates for small-ring cyclic allenes and butatrienes.

1 September 2018

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Anti-markovnikov N-H and O-H additions to electron-deficient olefins catalyzed by well-defined Cu(I) anilido, ethoxide, and phenoxide systems

1 September 2018

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Roots: from carbenes to allenes and coordination polymers. Ever present never twice the same

1 September 2018

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An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2.

1 September 2018

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Reactions and applications of titanium imido complexes

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Catalytic synthesis of tricyclic quinoline derivatives from the regioselective hydroamination and C-H bond activation reaction of benzocyclic amines and alkynes

1 September 2018

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Imidazo[1,5-a]pyridine: a versatile architecture for stable N-heterocyclic carbenes

1 September 2018

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Unusual reactivity of a nickel N-heterocyclic carbene complex: tert-butyl group cleavage and silicone grease activation

1 September 2018

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Evidence for the coexistence of two bond-stretch isomers in solution

1 September 2018

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A stable four-membered N-heterocyclic carbene

1 September 2018

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Asymmetric lithium(I) and copper(II) alkoxy-N-heterocyclic carbene complexes; crystallographic characterisation and Lewis acid catalysis.

1 September 2018

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Basicity of nucleophilic carbenes in aqueous and nonaqueous solvents-theoretical predictions.

1 September 2018

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Synthesis, reactivity, and ligand properties of a stable alkyl carbene

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Stable optically pure phosphino(silyl)carbenes: reagents for highly enantioselective cyclopropanation reactions

1 September 2018

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The 1,4-diphosphabuta-1,3-diene ligand for coordination of divalent group 13 and 14 elements: a density functional study

1 September 2018

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Gold(I)-catalyzed Conia-ene reaction of beta-ketoesters with alkynes

1 September 2018

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1,3-dialkyl- and 1,3-diaryl-3,4,5,6-tetrahydropyrimidin-2-ylidene rhodium(i) and palladium(II) complexes: synthesis, structure, and reactivity

1 September 2018

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Oxidative addition of imidazolium salts to Ni(0) and Pd(0): synthesis and structural characterization of unusually stable metal-hydride complexes

1 September 2018

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Amino-aryl-carbenes: alternative ligands for transition metals?

1 September 2018

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Sigma-bond stretching: a static approach for a dynamic process

1 September 2018

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Synthesis of carbenes through substitution reactions at a carbene center

1 September 2018

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Cyclopropenylium cations, cyclopropenones, and heteroanalogues-recent advances

1 September 2018

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Yttrium alkyl complexes with a sterically demanding benzamidinate ligand: synthesis, structure and catalytic ethene polymerisation

1 September 2018

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Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex

1 September 2018

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Structural Investigations into the retro-Diels-Alder Reaction. Experimental and Theoretical Studies.

1 September 2018

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Synthesis and rearrangement of diphosphorus analogues of amidinium salts

1 September 2018

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Singlet diradicals: from transition states to crystalline compounds

1 September 2018

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Mechanism and activity of ruthenium olefin metathesis catalysts

1 September 2018

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Chemistry and properties of cycloheptatetraene in the inner phase of a hemicarcerand

1 September 2018

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A cyclic carbanionic valence isomer of a carbocation: diphosphino analogs of diaminocarbocations

1 September 2018

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F-Block N-Heterocyclic Carbene Complexes

1 September 2018

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Anionic Amido N-Heterocyclic Carbenes: Synthesis of Covalently Tethered Lanthanide–Carbene Complexes

1 September 2018

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N-Heterocyclic Carbenes as Organocatalysts

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1 October 2018

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N-Heterocyclic Carbenes in Late Transition Metal Catalysis

3 December 2018

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Surveying Sterically Demanding N-Heterocyclic Carbene Ligands with Restricted Flexibility for Palladium-catalyzed Cross-Coupling Reactions

3 December 2018

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C4-bound imidazolylidenes: from curiosities to high-impact carbene ligands

3 December 2018

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Neutral Ligands with Exceptional Donor Ability for Palladium-Catalyzed Alkene Hydrogenation

3 December 2018

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Carbodiphosphoranes: The Chemistry of Divalent Carbon(0)

3 December 2018

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Sterically Demanding, Bioxazoline-Derived N-Heterocyclic Carbene Ligands with Restricted Flexibility for Catalysis

3 December 2018

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Organolanthanide-Catalyzed Hydroamination

3 December 2018

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An N-Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross-Coupling of Sterically Hindered Aryl Chlorides at Room Temperature

3 December 2018

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A stable chiral diaminocyclopropenylidene

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12 December 2020

Copper, Silver, and Gold Complexes in Hydrosilylation Reactions

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12 December 2020

Stable (amino)(phosphino)carbenes: difunctional molecules

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12 December 2020

Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos

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Bis-phosphorus stabilised carbene complexes

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Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines

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12 December 2020

One-step assembly of a chiral palladium bis(acyclic diaminocarbene) complex and its unexpected oxidation to a bis(amidine) complex

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12 December 2020

Synthesis and structural characterization of stable organogold(I) compounds. Evidence for the mechanism of gold-catalyzed cyclizations

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Gold catalysis: mild conditions for the synthesis of oxazoles from N-propargylcarboxamides and mechanistic aspects

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Carbenes stabilized by ylides: pushing the limits

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12 December 2020

Crystal structure of a silyl cation with no coordination to anion and distant coordination to solvent

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12 December 2020

An N,P-disubstituted-2-aminophosphaalkene and lithium and potassium complexes of the deprotonated "phosphaamidinate" anion

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12 December 2020

N-Acylation during the addition of carboxylic acids to N-tert-butylacylketenimines and the use of the reagent N-tert-butyl-5-methylisoxazolium perchlorate for peptide synthesis

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12 December 2020

Gold(III) porphyrin-catalyzed cycloisomerization of allenones

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12 December 2020

A singlet aryl-CF3 carbene: 2-benzothienyl(trifluoromethyl)carbene and interconversion with a strained cyclic allene

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12 December 2020

Computational study of carbon atom (3P and 1D) reaction with CH2O. Theoretical evaluation of 1B1 methylene production by C (1D)

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Acyclic diaminocarbenes: simple, versatile ligands for cross-coupling reactions

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12 December 2020

Quinone-annulated N-heterocyclic carbene-transition-metal complexes: observation of pi-backbonding using FT-IR spectroscopy and cyclic voltammetry

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12 December 2020

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12 December 2020

Grubbs’ Ruthenium-Carbenes Beyond the Metathesis Reaction: Less Conventional Non-Metathetic Utility

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12 December 2020

Recent developments in enantioselective gold(I) catalysis

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12 December 2020

Chemical bonding: Rethinking carbon

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12 December 2020

Elementary steps of gold catalysis: NMR spectroscopy reveals the highly cationic character of a "gold carbenoid"

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12 December 2020

Abnormal coordination of Arduengo's carbene upon reaction with M(3)(CO)(12) (M = Ru, Os)

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12 December 2020

Synthesis and ligand properties of a stable five-membered-ring vinylidenephosphorane

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12 December 2020

A Simple Catalyst for the Efficient Benzylation of Arenes by Using Alcohols, Ethers, Styrenes, Aldehydes, or Ketones

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N-heterocyclic carbenes: a new concept in organometallic catalysis

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Coordination chemistry of ene-1,1-diamines and a prototype "carbodicarbene"

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12 December 2020

Divalent E(0) compounds (E = Si-Sn)

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Synthesis of an Isolable Diphosphaisobenzene and a Stable Cyclic Allene with Six Ring Atoms Phosphorus Compounds, Part 147. This work was supported by the Fonds der Chemischen Industrie and the Deutsche Forschungsgemeinschaft (Graduate College "Phos

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1,2,4,6-Cycloheptatetraene: Room-Temperature Stabilization inside a Hemicarcerand This work was supported by the Petroleum Research Fund administered by the American Chemical Society, by Kansas State University, and by KSU Center for Basic Cancer Re

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Brønsted acid catalyzed addition of phenols, carboxylic acids, and tosylamides to simple olefins

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12 December 2020

Stable noncyclic singlet carbenes

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Air-stable secondary phosphine oxide as preligand for palladium-catalyzed intramolecular alpha-arylations with chloroarenes

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12 December 2020

Experimental investigation on the formation of carbon-bearing molecules in the interstellar medium via neutral-neutral reactions

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12 December 2020

On the electronic impact of abnormal C4-bonding in N-heterocyclic carbene complexes

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Geometry and aromaticity in highly strained heterocyclic allenes: characterization of a 2,3-didehydro-2H-thiopyran

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Synthesis of new pyrazolones as potent anti-inflammatory agents

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Aromaticity of Phosphorus Heterocycles

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Réplique: a new concept for bonding in carbodiphosphoranes?

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Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds

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Stable Versions of Transient Push-Pull Carbenes: Extending Lifetimes from Nanoseconds to Weeks

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Coinage metal-N-heterocyclic carbene complexes

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Gold-catalyzed intermolecular hydroamination of allenes with arylamines and resulting high chirality transfer

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Stable non-push-pull phosphanylcarbenes: NMR spectroscopic characterization of a methylcarbene

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A carbocyclic carbene as an efficient catalyst ligand for C-C coupling reactions

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Efficient Synthesis of 3-Aminocyclobut-2-en-1-ones: Squaramide Surrogates as Potent VLA-4 Antagonists

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Structure and reactivity of "unusual" N-heterocyclic carbene (NHC) palladium complexes synthesized from imidazolium salts

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Intramolecular C-N bond addition of amides to alkynes using platinum catalyst

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Au(I)-catalyzed highly efficient intermolecular hydroamination of alkynes

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In situ generation of novel acyclic diaminocarbene-copper complex

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12 December 2020

Carbocyclic carbene metal complexes

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A general method for the direct alpha-arylation of aldehydes with aryl bromides and chlorides

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C(NHC)2: divalent carbon(0) compounds with N-heterocyclic carbene ligands-theoretical evidence for a class of molecules with promising chemical properties

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The first asymmetric cyclopropanation reactions involving a stable carbene

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Reversible C-F bond formation and the Au-catalyzed hydrofluorination of alkynes

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12 December 2020

A stable P-heterocyclic carbene

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Generation and coordinating properties of a carbene bearing a phosphorus ylide: an intensely electron-donating ligand

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An unprecedented dinuclear alkylrhodium(III) complex built up by two 14-electron [RhCl2(alkyl)(PR3)] units

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The "Wanzlick Equilibrium" V.P.W.B. wishes to thank the Fonds der Chemischen Industrie for a Kekulé fellowship

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Gold(III)-catalyzed double hydroamination of o-alkynylaniline with terminal alkynes leading to N-vinylindoles

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A Homoleptic Carbene--Lithium Complex Homoleptic carbene complexes part 10. This work was supported by the Fonds der Chemischen Industrie, the Deutsche Forschungsgemeinschaft, and by the Studienstiftung des Deutschen Volkes. Part 9 ref. 14

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Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic Applications

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A Diaminocarbene-Phosphonium Ylide: Direct Access to C,C Chelating Ligands

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Synthesis, structure, and reductive elimination chemistry of three-coordinate arylpalladium amido complexes

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12 December 2020

Cyclic carbodiphosphoranes: strongly nucleophilic sigma-donor ligands

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12 December 2020

C6H4 valence bond isomers: a reactive bicyclopropenylidene

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Evidence for an Equilibrium between an N-heterocyclic Carbene and Its Dimer in Solution

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Polymer-supported well-defined metathesis catalysts

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First and second proton affinities of carbon bases

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Heterolytic dihydrogen activation by a frustrated carbene-borane Lewis pair

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12 December 2020

Cationic eta(1)/eta(2)-gold(I) complexes of simple arenes

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12 December 2020

Catalytic C-C Bond Formation through Selective Activation of C-F Bonds N-Heterocyclic Carbenes, Part 30. This work was supported by the Deutsche Forschungsgemeinschaft (DFG), the Bayerischer Forschungsverbund Katalyse (FORKAT), and the Fonds der Che

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12 December 2020

A Neutral Three-Coordinate Alkylrhodium(I) Complex: Stabilization of a 14-Electron Species by gamma-C-H Agostic Interactions with a Saturated Hydrocarbon Group This work was supported by the Deutsche Forschungsgemeinschaft (SFB 247, Graduate College

1 reference

12 December 2020

Divalent carbon(0) chemistry, part 2: Protonation and complexes with main group and transition metal Lewis acids

1 reference

12 December 2020

Triplet 1,3-diphenylpropynylidene (Ph-C-C-C-Ph)

1 reference

12 December 2020

Tuning the electronic properties of N-heterocyclic carbenes

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12 December 2020

Molecular electrostatic potentials of divalent carbon(0) compounds

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12 December 2020

Do extremely bent allenes exist?

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12 December 2020

A novel ylide-stabilized carbene; formation and electron donating ability of an amino(sulfur-ylide)carbene

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12 December 2020

Effective modulation of the donor properties of N-heterocyclic carbene ligands by "through-space" communication within a planar chiral scaffold

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12 December 2020

Equilibrium Ring-Closing Metathesis

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12 December 2020

A new route to acyclic diaminocarbenes via lithium-halogen exchange

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12 December 2020

Titanocene and zirconocene complexes of a phosphorus analog of an Arduengo's carbene: application in the synthesis of 1,3-diphosphafulvenes

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12 December 2020

Abnormal Carbenes as Ligands in Transition Metal Chemistry: Curiosities with Exciting Perspectives

1 reference

COCI

https://opencitations.net/index/coci/api/v1/citations/10.2533/CHIMIA.2009.105

Development of catalysts for the hydroamination of olefins

8 July 2023

1 reference

20 August 2023

https://opencitations.net/index/coci/api/v1/citations/10.1351/PAC200476030507

Divalent carbon(0) compounds

1 reference

20 August 2023

https://opencitations.net/index/coci/api/v1/citations/10.1351/PAC-CON-08-11-03

Golden opportunities in catalysis

1 reference

20 August 2023

https://opencitations.net/index/coci/api/v1/citations/10.1351/PAC200880051063

A Stable Thiazol-2-ylidene and Its Dimer

1 reference

15 September 2024

https://opencitations.net/index/api/v1/citations/10.1002/JLAC.199719970213

Identifiers

DOI

10.1002/ANIE.201000165

1 reference

23 August 2017

1 reference

PMC publication ID

3130005

23 August 2017

PubMed publication ID

20836099

1 reference

PMC publication ID

3130005