Experimental and computational studies on the mechanism of N-heterocycle C-H activation by Rh(I). (Q36977888)

17 August 2017

Experimental and computational studies on the mechanism of N-heterocycle C-H activation by Rh(I). (English)

1 reference

17 August 2017

4

Robert G Bergman

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17 August 2017

Sean H Wiedemann

1

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17 August 2017

Jared C Lewis

series ordinal

2

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17 August 2017

Jonathan A Ellman

series ordinal

3

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17 August 2017

language of work or name

English

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publication date

1 February 2006

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Journal of the American Chemical Society

17 August 2017

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17 August 2017

128

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17 August 2017

7

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17 August 2017

2452-2462

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Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference

17 August 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Catalytic C-h/olefin coupling

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Abnormal ligand binding and reversible ring hydrogenation in the reaction of imidazolium salts with IrH(5)(PPh(3))(2).

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Non-linear optimization of biochemical pathways: applications to metabolic engineering and parameter estimation

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

GEPASI: a software package for modelling the dynamics, steady states and control of biochemical and other systems

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Selective addition to iridium of aryl C-H bonds ortho to coordinating groups. Not chelation-assisted

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2.

27 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Intermolecular coupling of alkenes to heterocycles via C-H bond activation

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Palladium-catalyzed cyclization/carboalkoxylation of alkenyl indoles

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Theoretical studies of the oxidative addition of azolium salts to a model Wilkinson's catalyst

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Synthesis, reactivity, and ligand properties of a stable alkyl carbene

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Cross-coupling of sp(3) C-H bonds and alkenes: catalytic cyclization of alkene-amide substrates

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Formation and stability of N-heterocyclic carbenes in water: the carbon acid pKa of imidazolium cations in aqueous solution

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Platinum-catalyzed intramolecular alkylation of indoles with unactivated olefins

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Oxidative addition of imidazolium salts to Ni(0) and Pd(0): synthesis and structural characterization of unusually stable metal-hydride complexes

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Catalytic C-H bond functionalization with palladiumII: aerobic oxidative annulations of indoles

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Intermolecular coupling of isomerizable alkenes to heterocycles via rhodium-catalyzed C-H bond activation

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

A general and efficient copper catalyst for the amidation of aryl halides

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Intermediacy of an N-heterocyclic carbene complex in the catalytic C-H activation of a substituted benzimidazole

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Enantioselective organocatalytic indole alkylations. Design of a new and highly effective chiral amine for iminium catalysis

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

New strategies in organic catalysis: the first enantioselective organocatalytic Friedel-Crafts alkylation

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Annulation of alkenyl-substituted heterocycles via rhodium-catalyzed intramolecular C-H activated coupling reactions

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

A Mass Spectrometric Labeling Strategy for High-Throughput Reaction Evaluation and Optimization: Exploring C-H Activation This work was supported by the Director, Office of Energy Research, Office of Basic Energy Sciences, Chemical Sciences Division

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Microwave-Assisted C−H Bond Activation: A Rapid Entry into Functionalized Heterocycles

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2585050

Acylation of five-membered N-heteroaromatic compounds by ruthenium carbonyl-catalyzed direct carbonylation at a C-H bond

4 December 2018

1 reference

12 December 2020

A Search for pi/sigma Equilibria in Chiral Rhenium Imine Complexes of the Formula [(eta(5)-C(5)H(5))Re(NO)(PPh(3))(N(H)=C(CF(3))X)]( )TfO(-): Investigation of Electronic Effects upon the Binding Mode

1 reference

12 December 2020

1 reference

12 December 2020

Ru-, Rh-, and Pd-catalyzed C-C bond formation involving C-H activation and addition on unsaturated substrates: reactions and mechanistic aspects

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12 December 2020

Arylation of heterocycles via rhodium-catalyzed C-H bond functionalization

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12 December 2020

Ru(III)-catalyzed cyclization of arene-alkene substrates via intramolecular electrophilic hydroarylation

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12 December 2020

Structure and reactivity of "unusual" N-heterocyclic carbene (NHC) palladium complexes synthesized from imidazolium salts

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12 December 2020

Rhodium-catalyzed direct C-H addition of 4,4-dimethyl-2-oxazoline to alkenes

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12 December 2020

Transition-metal-catalyzed reactions involving imidazolium salt/N-heterocyclic carbene couples as substrates

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12 December 2020

A Mass Spectrometric Labeling Strategy for High-Throughput Reaction Evaluation and Optimization: Exploring C-H Activation

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12 December 2020

3,4-dihydro-2(1H)-quinazolinones

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12 December 2020

Biochemistry by numbers: simulation of biochemical pathways with Gepasi 3

1 reference

12 December 2020

Identifiers

DOI

10.1021/JA0576684

1 reference

17 August 2017

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17 August 2017

PubMed publication ID

16478202

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