Synthetic applications of gold-catalyzed ring expansions (Q35114640)

6 August 2017

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title

Synthetic applications of gold-catalyzed ring expansions (English)

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6 August 2017

2

Cristina Nevado

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6 August 2017

David Garayalde

1

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6 August 2017

language of work or name

English

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publication date

7 June 2011

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Beilstein Journal of Organic Chemistry

6 August 2017

published in

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6 August 2017

volume

7

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6 August 2017

page(s)

767-780

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Gold Catalysis: Recent Developments and Future Trends

6 August 2017

cites work

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Gold(I)-catalyzed cascade cyclization of allenyl epoxides.

9 July 2018

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Gold(I)-catalyzed enantioselective ring expansion of allenylcyclopropanols

9 July 2018

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Asymmetric synthesis of seven-membered carbocyclic rings via a sequential oxyanionic 5-exo-dig cyclization/claisen rearrangement process. Total synthesis of (-)-frondosin B.

9 July 2018

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Mechanistic studies on Au(I)-catalyzed [3,3]-sigmatropic rearrangements using cyclopropane probes

9 July 2018

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Gold-catalyzed cycloisomerizations of enynes: a mechanistic perspective

9 July 2018

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A gold(I)-catalyzed intramolecular reaction of propargylic/homopropargylic alcohols with oxirane

9 July 2018

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Fluorenes and styrenes by Au(I)-catalyzed annulation of enynes and alkynes

9 July 2018

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Catalytic carbophilic activation: catalysis by platinum and gold pi acids

9 July 2018

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Relativistic effects in homogeneous gold catalysis

9 July 2018

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Non-stabilized transition metal carbenes as intermediates in intramolecular reactions of alkynes with alkenes

9 July 2018

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Chemoselective CC Bond Cleavage of Epoxide Motifs: Gold(I)‐Catalyzed Diastereoselective [4 3] Cycloadditions of 1‐(1‐Alkynyl)oxiranyl Ketones and Nitrones

9 July 2018

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Gold‐Catalyzed Oxidative Ring Expansions and Ring Cleavages of Alkynylcyclopropanes by Intermolecular Reactions Oxidized by Diphenylsulfoxide

27 September 2018

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Mechanistic insights in gold-stabilized nonclassical carbocations: gold-catalyzed rearrangement of 3-cyclopropyl propargylic acetates.

27 September 2018

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Diversity of products in the gold-catalyzed cyclization of 1-epoxy-1-alkynylcyclopropanes by using 1-oxyallyl cations

27 September 2018

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Gold(I)-catalyzed ring expansions of unactivated alkynylcyclopropanes to (e)-2-alkylidenecyclobutanamines in the presence of sulfonamides

27 September 2018

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Silver- and gold-catalyzed intramolecular rearrangement of propargylic alcohols tethered with methylenecyclopropanes: stereoselective synthesis of allenylcyclobutanols and 1-vinyl-3-oxabicyclo[3.2.1]octan-8-one derivatives

27 September 2018

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Mechanistic studies and improvement of coinage metal-catalyzed transformation of alkynyloxiranes to furans: an alcohol addition-cyclization-elimination cascade.

27 September 2018

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Gold(I)-catalyzed cycloisomerization of arylvinylcyclopropenes: an efficient synthetic protocol for the construction of indene skeletons

27 September 2018

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Gold- and silver-catalyzed tandem amination/ring expansion of cyclopropyl methanols with sulfonamides as an expedient route to pyrrolidines.

27 September 2018

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Au(I)-catalyzed ring expanding cycloisomerizations: total synthesis of ventricosene

27 September 2018

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Au(I)-catalyzed efficient synthesis of functionalized bicyclo[3.2.0]heptanes

27 September 2018

1 reference

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Au-containing all-carbon 1,4-dipoles: generation and [4 2] annulation in the formation of carbo-/heterocycles

27 September 2018

1 reference

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A gold-catalyzed unique cycloisomerization of 1,5-enynes: efficient formation of 1-carboxycyclohexa-1,4-dienes and carboxyarenes

27 September 2018

1 reference

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Asymmetric catalysis of the [5 2] cycloaddition reaction of vinylcyclopropanes and pi-systems

27 September 2018

1 reference

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Gold(I)-catalyzed intramolecular acetylenic Schmidt reaction.

27 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3139417

Gold(I)-catalyzed ring expansion of cyclopropanols and cyclobutanols

27 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3139417

Transition metal-catalyzed intermolecular [5 2] and [5 2 1] cycloadditions of allenes and vinylcyclopropanes

27 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3139417

Catalytic regioselectivity control in ring-opening cycloisomerization of methylene- or alkylidenecyclopropyl ketones

27 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3139417

Development of novel type of transition metal-catalyzed cascade reactions utilizing small ring systems and the applications

27 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3139417

An Au-catalyzed cyclialkylation of electron-rich arenes with epoxides to prepare 3-chromanols

27 September 2018

1 reference

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2,3,4- or 2,3,5-Trisubstituted Furans: Catalyst-Controlled Highly Regioselective Ring-Opening Cycloisomerization Reaction of Cyclopropenyl Ketones

27 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3139417

The application of cyclobutane derivatives in organic synthesis

27 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3139417

Enantiomerically pure cyclobutane derivatives and their use in organic synthesis

27 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3139417

Gold-catalyzed organic reactions

27 September 2018

1 reference

12 December 2020

Highly diastereoselective gold- or copper-catalyzed formal [4 3] cycloaddition of 1-(1-alkynyl) cyclopropyl ketones and nitrones

1 reference

12 December 2020

Effects of haloniums on gold-catalyzed ring expansion of 1-oxiranyl-1-alkynylcyclopropanes

1 reference

12 December 2020

Gold-catalyzed cyclopenta- and cycloheptannulation cascades: a stereocontrolled approach to the scaffold of frondosins A and B

1 reference

12 December 2020

Gold(I)-catalyzed reaction of 1-(1-alkynyl)-cyclopropyl ketones with nucleophiles: a modular entry to highly substituted furans

1 reference

12 December 2020

Gold(I)-catalyzed rearrangement of alkynyloxiranes: a mild access to divinyl ketones

1 reference

12 December 2020

Gold(I)-catalyzed cascade cyclization reaction: highly regio- and diastereoselective intermolecular addition of water and alcohols to epoxy alkynes

1 reference

12 December 2020

Propargylic Esters in Gold Catalysis: Access to Diversity

1 reference

12 December 2020

Gold-catalyzed cycloisomerization of cyclopropyl alkynyl acetates: a versatile approach to 5-, 6-, and 7-membered carbocycles

1 reference

12 December 2020

"High noon" in gold catalysis: carbene versus carbocation intermediates

1 reference

12 December 2020

Studies toward frondosin A and its analogues. Formal total synthesis of ( /-)-frondosin A

1 reference

12 December 2020

Tuning the regioselectivity in the palladium(II)-catalyzed isomerization of alkylidene cyclopropyl ketones: a dramatic salt effect

1 reference

12 December 2020

Gold-catalyzed rearrangements: reaction pathways using 1-alkenyl-2-alkynylcyclopropane substrates

1 reference

12 December 2020

Prins cyclizations in Au-catalyzed reactions of enynes

1 reference

12 December 2020

Identifiers

DOI

10.3762/BJOC.7.87

1 reference

6 August 2017

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6 August 2017

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