Rhodium-catalyzed acyloxy migration of propargylic esters in cycloadditions, inspiration from the recent "gold rush" (Q26865118)

Dongxu Shu

series ordinal

2

1 reference

Casi M. Schienebeck

series ordinal

3

1 reference

Weiping Tang

series ordinal

4

1 reference

language of work or name

1 reference

7 December 2012

1 reference

published in

Chemical Society Reviews

1 reference

volume

41

1 reference

issue

23

1 reference

page(s)

7698-711

1 reference

The Meyer–Schuster rearrangement for the synthesis of α,β-unsaturated carbonyl compounds

cites work

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Gold catalysis in total synthesis—an update

7 April 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Recent developments in gold-catalyzed cycloaddition reactions

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Chiral (acyclic diaminocarbene)gold(I)-catalyzed dynamic kinetic asymmetric transformation of propargyl esters

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

The use of Br/Cl to promote regioselective gold-catalyzed rearrangement of propargylic carboxylates: an efficient synthesis of (1Z, 3E)-1-bromo/chloro-2-carboxy-1,3-dienes

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Gold-catalyzed Intermolecular [4C 3C] Cycloaddition Reactions

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Mechanistic studies on Au(I)-catalyzed [3,3]-sigmatropic rearrangements using cyclopropane probes

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Mechanistically diverse copper-, silver-, and gold-catalyzed acyloxy and phosphatyloxy migrations: efficient synthesis of heterocycles via cascade migration/cycloisomerization approach

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Recent developments in the metal-catalyzed reactions of metallocarbenoids from propargylic esters

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Rhodium-catalyzed carbonylation of 3-acyloxy-1,4-enynes for the synthesis of cyclopentenones

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Rhodium-catalyzed intra- and intermolecular [5 2] cycloaddition of 3-acyloxy-1,4-enyne and alkyne with concomitant 1,2-acyloxy migration

31 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Rhodium-catalyzed 1,3-acyloxy migration and subsequent intramolecular [4 2] cycloaddition of vinylallene and unactivated alkyne

31 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Rhodium‐Catalyzed Ring Expansion of Cyclopropanes to Seven‐membered Rings by 1,5 CC Bond Migration

31 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Interception of a Rautenstrauch Intermediate by Alkynes for [5 2] Cycloaddition: Rhodium‐Catalyzed Cycloisomerization of 3‐Acyloxy‐4‐ene‐1,9‐diynes to Bicyclo[5.3.0]decatrienes

31 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Synthesis of Highly Functionalized Cyclohexenone Rings: Rhodium‐Catalyzed 1,3‐Acyloxy Migration and Subsequent [5 1] Cycloaddition

31 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Gold-catalyzed [3 3]-annulation of azomethine imines with propargyl esters

31 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Synthesis of azepines by a gold-catalyzed intermolecular [4 3]-annulation

31 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Fluorenes and styrenes by Au(I)-catalyzed annulation of enynes and alkynes

31 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Gold(I)-catalyzed stereoselective olefin cyclopropanation.

31 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Pt-catalyzed pentannulations from in situ generated metallo-carbenoids utilizing propargylic esters

31 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3491182

Umlagerung tertiärer Äthinyl-carbinole in ungesättigte Ketone

31 May 2018

1 reference

Ungesättigte Aldehyde aus Acetylen-alkoholen

21 January 2018

1 reference

New insights on the mechanism of the transition-metal stereoselective olefin cyclopropanation

21 January 2018

1 reference

Gold- and platinum-catalyzed cycloisomerization of enynyl esters versus allenenyl esters: an experimental and theoretical study

21 January 2018

1 reference

Mechanistic insights in gold-stabilized nonclassical carbocations: gold-catalyzed rearrangement of 3-cyclopropyl propargylic acetates.

21 January 2018

1 reference

Tandem au-catalyzed 3,3-rearrangement-[2 2] cycloadditions of propargylic esters: expeditious access to highly functionalized 2,3-indoline-fused cyclobutanes.

21 January 2018

1 reference

Gold-catalyzed tandem 1,3-migration/[2 2] cycloaddition of 1,7-enyne benzoates to azabicyclo[4.2.0]oct-5-enes.

21 January 2018

1 reference

PtCl2-catalyzed rapid access to tetracyclic 2,3-indoline-fused cyclopentenes: reactivity divergent from cationic Au(I) catalysis and synthetic potential

21 January 2018

1 reference

Platinum-catalyzed cycloisomerization reaction of 1,6-enyne coupling with rearrangement of propargylic esters

21 January 2018

1 reference

Gold-catalyzed stereocontrolled oxacyclization/[4 2]-cycloaddition cascade of ketone-allene substrates

21 January 2018

1 reference

A gold-catalyzed entry into the sesquisabinene and sesquithujene families of terpenoids and formal total syntheses of cedrene and cedrol

21 January 2018

1 reference

Ruthenium-Catalyzed Cyclopropanation of Alkenes Using Propargylic Carboxylates as Precursors of Vinylcarbenoids

21 January 2018

1 reference

Asymmetric synthesis of medium-sized rings by intramolecular Au(I)-catalyzed cyclopropanation

21 January 2018

1 reference

Synthesis of benzonorcaradienes by gold(I)-catalyzed [4 3] annulation.

21 January 2018

1 reference

A highly efficient preparative method of alpha-ylidene-beta-diketones via Au(III)-catalyzed acyl migration of propargylic esters.

21 January 2018

1 reference

Synthesis of 2-cyclopentenones by gold(I)-catalyzed Rautenstrauch rearrangement.

21 January 2018

1 reference

Transition Metal-Catalyzed Carbocyclizations in Organic Synthesis

21 January 2018

1 reference

Iridium-Catalyzed [5 1] Cycloaddition: Allenylcyclopropane as a Five-Carbon Assembling Unit

21 January 2018

1 reference

12 December 2020

Transition Metal-Mediated Cycloaddition Reactions

1 reference

12 December 2020

CpRuCl(PPh3)2-catalyzed cyclopropanation of bicyclic alkenes with tertiary propargylic acetates

1 reference

12 December 2020

Gold(I) catalyzed isomerization of 5-en-2-yn-1-yl acetates: an efficient access to acetoxy bicyclo[3.1.0]hexenes and 2-cycloalken-1-ones

1 reference

12 December 2020

Propargylic Esters in Gold Catalysis: Access to Diversity

1 reference

12 December 2020

Rearrangement of propargylic esters: metal-based stereospecific synthesis of (E)- and (Z)-knoevenagel derivatives

1 reference

12 December 2020

Golden Carousel in Catalysis: The Cationic Gold/Propargylic Ester Cycle

1 reference

12 December 2020

Synthesis of cyclobutenes by highly selective transition-metal-catalyzed ring expansion of cyclopropanes

1 reference

12 December 2020

Synthesis of (-)-cubebol by face-selective platinum-, gold-, or copper-catalyzed cycloisomerization: evidence of chirality transfer and mechanistic insights

1 reference

12 December 2020

Pt-catalyzed tandem 1,2-acyloxy migration/intramolecular [3 2] cycloaddition of enynyl esters

1 reference

12 December 2020

Cationic rhodium(I) complex-catalyzed [3 2] and [2 1] cycloadditions of propargyl esters with electron-deficient alkynes and alkenes

1 reference

12 December 2020

Synthesis of functionalized resorcinols by rhodium-catalyzed [5 1] cycloaddition reaction of 3-acyloxy-1,4-enynes with CO

1 reference

12 December 2020

Rh-catalyzed [7 1] cycloaddition of buta-1,3-dienylcyclopropanes and CO for the synthesis of cyclooctadienones

1 reference

12 December 2020

Gold-catalyzed cyclopenta- and cycloheptannulation cascades: a stereocontrolled approach to the scaffold of frondosins A and B

1 reference

12 December 2020

Gold‐Catalyzed [3 2] Cycloaddition/Hydrolytic Michael Addition/Retro‐Aldol Reactions of Propargylic Esters Tethered to Cyclohexadienones

1 reference

12 December 2020

Au-Catalyzed Piperidine Synthesis via Tandem Acyloxy Migration/Intramolecular [3 2] Cycloaddition of Enynyl Esters

1 reference

12 December 2020

Rh(I)-catalyzed [5 1] cycloaddition of vinylcyclopropanes and CO for the synthesis of α,β- and β,γ-cyclohexenones

1 reference

12 December 2020

Factors controlling the equilibrium of Pt-catalyzed [1,2]- versus [1,3]-acyloxy migration

1 reference

12 December 2020

Rh-catalyzed [5 1] and [4 1] cycloaddition reactions of 1,4-enyne esters with CO: a shortcut to functionalized resorcinols and cyclopentenones

1 reference

12 December 2020

Rhodium-Catalyzed Intermolecular [4 2] Cycloaddition of Unactivated Substrates

1 reference

12 December 2020

Identifiers

0 references

1 reference

PubMed publication ID

22895533

1 reference