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Wettability can be defined as the work necessary to separate a wetting fluid from a solid. In the subsurface we would generally consider water the wetting fluid and the solid would be grains of quartz in a sandstone, calcite in a limestone, etc. The adhesive force or attraction of the wetting fluid to the solid in any oil-water-rock system is the result of the combined interfacial energy of the oil-water, oil-rock, and water-rock surfaces.

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