- As a teenager, Maxine played rugby league for her local Wigan Ladies team.
- Revealed in an interview in August 2014 that over the years she has suffered two miscarriages and undergone several failed attempts at IVF treatment.
- Some of her fellow 1998 graduates from Royal Academy of Dramatic Arts, includes Tobias Menzies, Robert Wilfort, Sally Hawkins and Joanna Page.
- In Shameless (2004), her character's boyfriend remarks that her passport photo resembles Myra Hindley. She later starred as Hindley in See No Evil: The Moors Murders (2006).
- First became interested in acting at age 13, when she joined the Bolton Octagon Theatre's youth club.
- Activist for just causes.
- Humanitarian.
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