Here's the final thing to show how Luna would appear in the game Star Fox Assault. Being a member of my team Star Flight we actually met and ran into Star Wolf with a situation that required they needed help before Panther joined Wolf's team. The perfect time Luna could have appeared in the game was at the defense of the orbital gate.

As for her and Wolf she knew exactly what he was and yet there were things like I've said before that she found to love. And Wolf saw her as more than just another female; her kindness, love, and sweetness but also being a great pilot was something that was able to change him somewhat. She is one of the few Wolf could never harm and in the end like with the other couples, the two came together, a perfect wolf couple and match made in heaven.