Aluminium oxide

Aluminium oxide, also known as aluminum oxide, is a chemical compound made from aluminium and oxygen. Its chemical formula is Al₂O₃. It is a normally white, powdery solid. It does not exist in a particular form. It can dissolve in acids and bases. It is used as an abrasive (sandpaper is an abrasive). It comes in bauxite and corundum. It does not melt easily. It is dissolved in a cryolite melt and electrolyzed to make aluminium.

Natural occurrence

Corundum is the most common naturally occurring crystalline form of aluminium oxide.^[1] Rubies and sapphires are types of corundum. The reason why they have different colors is because there are other elements in it.^[2]^[3]

Properties

Al₂O₃ is an electrical insulator but it has a high thermal conductivity (30 Wm⁻¹K⁻¹).^[4] Aluminium oxide is insoluble in water. Its most common occurring crystalline form, called corundum or α-aluminium oxide.

Aluminium oxide is the reason why aluminium cannot corrode. When aluminium reacts with atmospheric oxygen, a thin layer of aluminium oxide (4 nm thickness) forms on any exposed aluminium surface.^[5] This layer protects the metal from more oxidation.

Aluminium oxide is an amphoteric substance, meaning it can react with both acids and bases, such as hydrofluoric acid and sodium hydroxide.

References

↑ Elam, J. W. (October 2010). Atomic Layer Deposition Applications 6. The Electrochemical Society. ISBN 9781566778213.
↑ "Deltalumite".
↑ "List of Minerals". 21 March 2011.
↑ Material Properties Data: Alumina (Aluminum Oxide) Archived 2010-04-01 at the Wayback Machine. Makeitfrom.com. Retrieved on 2013-04-17.
↑ Campbell, Timothy; Kalia, Rajiv; Nakano, Aiichiro; Vashishta, Priya; Ogata, Shuji; Rodgers, Stephen (1999). "Dynamics of Oxidation of Aluminium Nanoclusters using Variable Charge Molecular-Dynamics Simulations on Parallel Computers" (PDF). Physical Review Letters. 82 (24): 4866. Bibcode:1999PhRvL..82.4866C. doi:10.1103/PhysRevLett.82.4866. Archived (PDF) from the original on 2010-07-01.

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[1] Elam, J. W. (October 2010). Atomic Layer Deposition Applications 6. The Electrochemical Society. ISBN 9781566778213.

[2] "Deltalumite".

[3] "List of Minerals". 21 March 2011.

[properties-4] Material Properties Data: Alumina (Aluminum Oxide) Archived 2010-04-01 at the Wayback Machine. Makeitfrom.com. Retrieved on 2013-04-17.

[5] Campbell, Timothy; Kalia, Rajiv; Nakano, Aiichiro; Vashishta, Priya; Ogata, Shuji; Rodgers, Stephen (1999). "Dynamics of Oxidation of Aluminium Nanoclusters using Variable Charge Molecular-Dynamics Simulations on Parallel Computers" (PDF). Physical Review Letters. 82 (24): 4866. Bibcode:1999PhRvL..82.4866C. doi:10.1103/PhysRevLett.82.4866. Archived (PDF) from the original on 2010-07-01.

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