As a conceptual help before embarking on processing the Libris works database, it would be nice to have a couple example items that demonstrate the work/edition distinction.
Have a look at https://www.wikidata.org/wiki/Wikidata:WikiProject_Books to see how it can be done. Select a work from the svwp source dataset.
A difficulty is that the Work layer in Libris XL is still not functional – this looks like manually created example items. Meaning we can't assign Libris URI's to works that don't exist...