Fluoride nitrate

Fluoride nitrates are mixed anion compounds that contain both fluoride ions and nitrate ions. Compounds are known for some amino acids and for some heavy elements. Some transition metal fluorido complexes that are nitrates are also known. There are also fluorido nitrato complex ions known in solution.

List

name	formula	mw	crystal system	space group	unit cell Å	volume	density	comment	reference
L-Argininium	L-Arg²•F⁻•NO₃⁻		triclinic	P1	a=5.0130 b=10.6161 c=11.0352 α=87.471 β=86.038 γ=78.157 Z=2				^[1]
	2L-Arg²•F⁻•3NO₃⁻•HF		orthorhombic	P2₁2₁2₁	a=7.3960 b=12.8672 c=26.990 Z=4				^[1]
L-histidine	L-His²•F⁻•NO₃⁻								^[1]
	[Cr(NH₃)₅F](NO₃)₂								^[2]
hexakis(1H-imidazole)-cobalt(ii) fluoride nitrate tetrahydrate	[Co(Im)₆][F·NO₃•(H₂O)₄]		hexagonal	P6₃/m	a 8.972 c 21.077 Z=2	1469.3	1.402	pink	^[3]
	[Co(NH₃)₄(OH)F]NO₃								^[4]
	[Co(NH₃)₅F](NO₃)₂								^[5]
	[Co(NH₃)₆]F(NO₃)₂								^[4]
	[Co(en)₂F₂]NO₃								^[4]
	[As(ONO₂)₄][AsF₆]⁻							pale yellow; hydroscopic	^[6]
	[Zr₂F₃OH(NO₃)₂(H₂O)₅]²							in solution	^[7]
	SnF₂(ONO₂)₂								^[6]
	SnF₃(ONO₂)							stable < 40 °C; hydroscopic	^[6]
	SbF(ONO₂)₄								^[6]
	SbF₃(ONO₂)₂								^[6]
Xenon fluoride nitrate	FXeONO₂		monoclinic		a = 4.6663 b = 8.799 c = 9.415 β = 90.325°	386.6	3.648
	CsFHONO₂								^[8]
	[HfF₄NO₃]⁻							in solution	^[7]
	[HfF₃(NO₃)₂]⁻							in solution	^[7]
	Hg₃O₂(NO₃)F		orthorhombic	Pnma	a=7.547 b=10.990 c=6.9906			birefringence Δn = 0.23 @ 1064 nm	^[9]
	Pb₃F₅NO₃		triclinic	P1	a 7.3796 b 12.147 c 16.8549, α 100.46° β 90.076° γ 95.517°			layered; stable to 450 °C	^[10]^[11]
	Pb(OF)Cu₃(SeO₃)₂(NO₃)		trigonal	R3m	a 6.6973 c 18.5548 Z=3	720.75	5.175	yellow; stable to 400 °C	^[12]
	PbCdF(SeO₃)(NO₃)		orthorhombic	Pca2₁	a=11.121 b=10.366 c=5.3950			NLO 2.6×KDP; band gap 4.42 eV	^[13]
	BaPb₂F₅NO₃								^[14]
	Bi₂OF₃(NO₃)		hexagonal	P6₃/m				band gap 3.5 eV	^[15]
	Bi₆O₆F₅(NO₃)		trigonal	R3				band gap 4.0 eV	^[15]
	[(UO₂)₄F₁₃][Sr₃(H₂O)₈](NO₃)·H₂O	1814.13	triclinic	P1	a = 10.793, b = 10.918, c = 13.231 α = 92.570°, β = 109.147°, γ = 92.778° Z = 2.	1468.1	4.105	yellow	^[16]

References

^ ^a ^b ^c Fleck, Michel; Petrosyan, Aram M. (2014). Salts of amino acids: crystallization, structure and properties. Cham Heidelberg: Springer. pp. 503–507. ISBN 978-3-319-06298-3.
^ Merabet, K. E.; Burriel, Ramón; Carlin, Richard L. (1988-12-01). "Magnetochemistry of chromium(III): Linear-chain – to – simple-cubic crossover magnetic interactions in several halopentammines". Physical Review B. 38 (16): 11589–11592. doi:10.1103/PhysRevB.38.11589. ISSN 0163-1829.
^ Jian, Fang Fang; Liu, E.; Ma, Jun Ying (2018). "Interesting fluorine anion water clusters [F − ·(H 2 O) n ] in metal complex crystals". CrystEngComm. 20 (27): 3849–3857. doi:10.1039/C8CE00532J. ISSN 1466-8033.
^ ^a ^b ^c Chan, S. C.; Poon, C. K. (1966). "Preparation, properties, and isomerisation of aquofluorobis(ethylenediamine)cobalt(III) cations". Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 146–150. doi:10.1039/j19660000146. ISSN 0022-4944.
^ Balt, S.; Pothoff, G. F. (April 1975). "A conductance study of some cobalt(III) complexes in liquid ammonia". Journal of Solution Chemistry. 4 (4): 359–367. doi:10.1007/BF00650393. ISSN 0095-9782. S2CID 97374902.
^ ^a ^b ^c ^d ^e Weidlein, Johann; Dehnicke, Kurt (September 1965). "Über die Fluoridnitrate der Elemente Arsen, Antimon und Zinn". Chemische Berichte. 98 (9): 3053–3059. doi:10.1002/cber.19650980939. ISSN 0009-2940.
^ ^a ^b ^c Bertoli, Alexandre C.; Miguita, Ana Gabriella C.; Mingote, Raquel M.; Augusti, Rodinei; Duarte, Hélio A. (2021-03-26). "Unveiling the Zirconium and Hafnium Speciation in Fluoride‐Nitric Acid Solutions by Paper Spray Ionization Mass Spectrometry Combined with DFT Calculations". European Journal of Inorganic Chemistry. 2021 (12): 1175–1185. doi:10.1002/ejic.202001140. ISSN 1434-1948. S2CID 233628149.
^ Al-Zamil, Nabila; Delf, Brian W.; Gillard, R.D. (January 1980). "The fluoro-nitrato-hydrogenate(I) anion, [F··H··ONO2]−". Journal of Inorganic and Nuclear Chemistry. 42 (8): 1117–1122. doi:10.1016/0022-1902(80)80420-9.
^ Lv, Yi-Lei; Huai, Lei; Wei, Yu-Long; Ma, Liang; Wei, Yue-Qi; Liu, Wenlong; Tang, Ru-Ling (2023). "Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) ] ∞ cationic framework and excellent optical anisotropy". Inorganic Chemistry Frontiers. 10 (16): 4845–4853. doi:10.1039/D3QI01146A. ISSN 2052-1553.
^ Rogow, David L.; Russell, Matthew P.; Wayman, Lora M.; Swanson, Claudia H.; Oliver, Allen G.; Oliver, Scott R. J. (2010-02-03). "Hydrothermal Synthesis and Characterization of Three Cationic Inorganic−Organic Hybrid Materials Based on Lead Fluoride". Crystal Growth & Design. 10 (2): 823–829. doi:10.1021/cg9011923. ISSN 1528-7483.
^ Tran, Dat T.; Zavalij, Peter Y.; Oliver, Scott R. J. (2002-04-01). "Pb 3 F 5 NO 3 , a Cationic Layered Material for Anion-Exchange". Journal of the American Chemical Society. 124 (15): 3966–3969. doi:10.1021/ja017333w. ISSN 0002-7863. PMID 11942835.
^ Zhang, Mengsi; Zhao, Zhiying; Zhang, Wanwan; Li, Jinyang; Huang, Xiaoying; He, Zhangzhen (2020). "Pb(OF)Cu 3 (SeO 3 ) 2 (NO 3 ): a selenite fluoride nitrate with a breathing kagomé lattice". Chemical Communications. 56 (80): 11965–11968. doi:10.1039/D0CC03684F. ISSN 1359-7345. PMID 33033813. S2CID 222235842.
^ Ma, Yun-Xiang; Hu, Chun-Li; Li, Bing-Xuan; Kong, Fang; Mao, Jiang-Gao (2018-09-17). "PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units". Inorganic Chemistry. 57 (18): 11839–11846. doi:10.1021/acs.inorgchem.8b02044. ISSN 0020-1669. PMID 30160946. S2CID 52136440.
^ CHARKIN, DMITRI O. (2019). "NEW STRUCTURAL ANALOGIES AMONG LAYERED NITRATES AND HALIDES: SYNTHESIS AND STRUCTURE OF A NEW SILLéN-DERIVED FLUORIDE NITRATE, BAPB2F5NO3".
^ ^a ^b Cho, Eun Jeong; Oh, Seung-Jin; Jo, Hongil; Lee, Junsu; You, Tae-Soo; Ok, Kang Min (2019-02-04). "Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties". Inorganic Chemistry. 58 (3): 2183–2190. doi:10.1021/acs.inorgchem.8b03343. ISSN 0020-1669.
^ Jouffret, Laurent J.; Hiltbrunner, Jean-Michel; Rivenet, Murielle; Sergent, Nicolas; Obbade, Saïd; Avignant, Daniel; Dubois, Marc (2016-12-05). "Insight into the Uranyl Oxyfluoride Topologies through the Synthesis, Crystal Structure, and Evidence of a New Oxyfluoride Layer in [(UO 2 ) 4 F 13 ][Sr 3 (H 2 O) 8 ](NO 3 )·H 2 O". Inorganic Chemistry. 55 (23): 12185–12192. doi:10.1021/acs.inorgchem.6b01765. ISSN 0020-1669. PMID 27934437.

[:1-1] Fleck, Michel; Petrosyan, Aram M. (2014). Salts of amino acids: crystallization, structure and properties. Cham Heidelberg: Springer. pp. 503–507. ISBN 978-3-319-06298-3.

[2] Merabet, K. E.; Burriel, Ramón; Carlin, Richard L. (1988-12-01). "Magnetochemistry of chromium(III): Linear-chain – to – simple-cubic crossover magnetic interactions in several halopentammines". Physical Review B. 38 (16): 11589–11592. doi:10.1103/PhysRevB.38.11589. ISSN 0163-1829.

[3] Jian, Fang Fang; Liu, E.; Ma, Jun Ying (2018). "Interesting fluorine anion water clusters [F − ·(H 2 O) n ] in metal complex crystals". CrystEngComm. 20 (27): 3849–3857. doi:10.1039/C8CE00532J. ISSN 1466-8033.

[:0-4] Chan, S. C.; Poon, C. K. (1966). "Preparation, properties, and isomerisation of aquofluorobis(ethylenediamine)cobalt(III) cations". Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 146–150. doi:10.1039/j19660000146. ISSN 0022-4944.

[5] Balt, S.; Pothoff, G. F. (April 1975). "A conductance study of some cobalt(III) complexes in liquid ammonia". Journal of Solution Chemistry. 4 (4): 359–367. doi:10.1007/BF00650393. ISSN 0095-9782. S2CID 97374902.

[:2-6] Weidlein, Johann; Dehnicke, Kurt (September 1965). "Über die Fluoridnitrate der Elemente Arsen, Antimon und Zinn". Chemische Berichte. 98 (9): 3053–3059. doi:10.1002/cber.19650980939. ISSN 0009-2940.

[:3-7] Bertoli, Alexandre C.; Miguita, Ana Gabriella C.; Mingote, Raquel M.; Augusti, Rodinei; Duarte, Hélio A. (2021-03-26). "Unveiling the Zirconium and Hafnium Speciation in Fluoride‐Nitric Acid Solutions by Paper Spray Ionization Mass Spectrometry Combined with DFT Calculations". European Journal of Inorganic Chemistry. 2021 (12): 1175–1185. doi:10.1002/ejic.202001140. ISSN 1434-1948. S2CID 233628149.

[8] Al-Zamil, Nabila; Delf, Brian W.; Gillard, R.D. (January 1980). "The fluoro-nitrato-hydrogenate(I) anion, [F··H··ONO2]−". Journal of Inorganic and Nuclear Chemistry. 42 (8): 1117–1122. doi:10.1016/0022-1902(80)80420-9.

[9] Lv, Yi-Lei; Huai, Lei; Wei, Yu-Long; Ma, Liang; Wei, Yue-Qi; Liu, Wenlong; Tang, Ru-Ling (2023). "Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) ] ∞ cationic framework and excellent optical anisotropy". Inorganic Chemistry Frontiers. 10 (16): 4845–4853. doi:10.1039/D3QI01146A. ISSN 2052-1553.

[10] Rogow, David L.; Russell, Matthew P.; Wayman, Lora M.; Swanson, Claudia H.; Oliver, Allen G.; Oliver, Scott R. J. (2010-02-03). "Hydrothermal Synthesis and Characterization of Three Cationic Inorganic−Organic Hybrid Materials Based on Lead Fluoride". Crystal Growth & Design. 10 (2): 823–829. doi:10.1021/cg9011923. ISSN 1528-7483.

[11] Tran, Dat T.; Zavalij, Peter Y.; Oliver, Scott R. J. (2002-04-01). "Pb 3 F 5 NO 3 , a Cationic Layered Material for Anion-Exchange". Journal of the American Chemical Society. 124 (15): 3966–3969. doi:10.1021/ja017333w. ISSN 0002-7863. PMID 11942835.

[12] Zhang, Mengsi; Zhao, Zhiying; Zhang, Wanwan; Li, Jinyang; Huang, Xiaoying; He, Zhangzhen (2020). "Pb(OF)Cu 3 (SeO 3 ) 2 (NO 3 ): a selenite fluoride nitrate with a breathing kagomé lattice". Chemical Communications. 56 (80): 11965–11968. doi:10.1039/D0CC03684F. ISSN 1359-7345. PMID 33033813. S2CID 222235842.

[13] Ma, Yun-Xiang; Hu, Chun-Li; Li, Bing-Xuan; Kong, Fang; Mao, Jiang-Gao (2018-09-17). "PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units". Inorganic Chemistry. 57 (18): 11839–11846. doi:10.1021/acs.inorgchem.8b02044. ISSN 0020-1669. PMID 30160946. S2CID 52136440.

[14] CHARKIN, DMITRI O. (2019). "NEW STRUCTURAL ANALOGIES AMONG LAYERED NITRATES AND HALIDES: SYNTHESIS AND STRUCTURE OF A NEW SILLéN-DERIVED FLUORIDE NITRATE, BAPB2F5NO3".

[:4-15] Cho, Eun Jeong; Oh, Seung-Jin; Jo, Hongil; Lee, Junsu; You, Tae-Soo; Ok, Kang Min (2019-02-04). "Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties". Inorganic Chemistry. 58 (3): 2183–2190. doi:10.1021/acs.inorgchem.8b03343. ISSN 0020-1669.

[16] Jouffret, Laurent J.; Hiltbrunner, Jean-Michel; Rivenet, Murielle; Sergent, Nicolas; Obbade, Saïd; Avignant, Daniel; Dubois, Marc (2016-12-05). "Insight into the Uranyl Oxyfluoride Topologies through the Synthesis, Crystal Structure, and Evidence of a New Oxyfluoride Layer in [(UO 2 ) 4 F 13 ][Sr 3 (H 2 O) 8 ](NO 3 )·H 2 O". Inorganic Chemistry. 55 (23): 12185–12192. doi:10.1021/acs.inorgchem.6b01765. ISSN 0020-1669. PMID 27934437.

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