File:Ellingham-Richardson.svg

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English: Ellingham-Richardson diagram for high temperature oxidation (dry corrosion)
Français : Diagramme d'Ellingham-Richardson pour l'oxydation à haute température (corrosion sèche)
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Source Own work
Author Christophe Dang Ngoc Chan(cdang)
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Diagramme d'Ellingham-Richardson : oxydation du métal ou réduction de l'oxyde selon la pression partielle de dioxygène et la température (corrosion à haute température).

On trace l'enthalpie molaire partielle (énergie libre de Gibbs) de la réaction d'oxydation ΔG0 en fonction de la température (la loi est assimilée à une droite), ainsi que l'enthalpie du dioxygène -RTln(PO2) pour une pression partielle donnée (en atmosphères). L'intersection des deux droites donne la température en dessous de laquelle l'oxyde est stable pour la pression de dioxygène donnée ; au-dessus de cette température, c'est le métal qui est stable. Si le gaz n'est pas du dioxygène mais par exemple de la vapeur d'eau ou du dioxyde de carbone, on se ramène à la pression partielle de dioxygène équivalente (c'est-à-dire la pression partielle de dioxygène qui a la même activité chimique que le gaz en question).

Ce diagramme est utilisé notamment en corrosion à haute température.

Notez qu'il faudrait en toute rigueur écrire -RTln(PO2/P0) où P0 est la pression servant à définir ΔG0 (ou "pression normale"), en l'occurence 1 atm.


Ellingham-Richardson diagram: oxidation of the metal or reduction of the oxide according to the partial pressure of dioxygen and the temperature

The partial molar enthalpy (Gibbs free energy) ΔG0 of the oxidation reaction is drawn versus the temperature (the law is approximated by a linear law), and the enthalpy of dioxygen -RTln(PO2) for a given partial pressure (in atmospheres). The intercept of the two lines give the threshold temperature: the oxide is stable below this temperature for the partial pressure, above this temperature, the metal is stable. Si le gaz n'est pas du dioxygène mais par exemple de la vapeur d'eau ou du dioxyde de carbone, on se ramène à la pression partielle de dioxygène équivalente (c'est-à-dire la pression partielle de dioxygène qui a la même activité chimique que le gaz en question).

Ce diagramme est utilisé notamment en corrosion à haute température.

Notez qu'il faudrait en toute rigueur écrire -RTln(PO2/P0) où P0 est la pression servant à définir ΔG0 (ou "pression normale"), en l'occurence 1 atm.

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Date/TimeThumbnailDimensionsUserComment
current14:56, 29 June 2006Thumbnail for version as of 14:56, 29 June 2006524 × 744 (26 KB)Cdang (talk | contribs)plains SVG (maybe better behaviour)
07:19, 3 May 2006Thumbnail for version as of 07:19, 3 May 2006524 × 744 (28 KB)Cdang (talk | contribs)Rendering problem: * D in symbol font replaced by unicode character Δ * default (but unusual) font replaced by Arial
08:08, 27 April 2006Thumbnail for version as of 08:08, 27 April 2006524 × 744 (28 KB)Cdang (talk | contribs)problems should be fixed
18:39, 26 April 2006Thumbnail for version as of 18:39, 26 April 2006524 × 744 (37 KB)Cdang (talk | contribs)2nd try --- some problems fixed
08:26, 25 April 2006Thumbnail for version as of 08:26, 25 April 2006524 × 744 (39 KB)Cdang (talk | contribs){{Information| |Description=Ellingham-Richardson diagram |Source= |Date=25 April 2006 |Author=Christophe Dang Ngoc Chan(user:cdang |Permission= |other_versions= }} Diagramme d'Ellingham-Richardson : oxydation du métal ou réduction de l'oxyde selon

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