Sodium deuteroxide

Sodium deuteroxide^[1]
Names
	IUPAC name Sodium deuteroxide
	Other names Deuterated sodium hydroxide; Sodium hydroxide-d;
Identifiers
CAS Number	14014-06-3;
3D model (JSmol)	Interactive image;
ChemSpider	9193979;
ECHA InfoCard	100.034.373
EC Number	237-825-2;
PubChem CID	23676750;
CompTox Dashboard (EPA)	DTXSID80930715 ;
	InChI InChI=1S/Na.H2O/h;1H2/q 1;/p-1/i/hD Key: HEMHJVSKTPXQMS-DYCDLGHISA-M;
	SMILES [Na ].[O-][2H];
Properties
Chemical formula	NaOD or NaO2H
Molar mass	41.003 g/mol
Appearance	White solid
Solubility in water	Soluble
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H290, H314
Precautionary statements	P260, P264, P280, P301 P330 P331, P303 P361 P353, P304 P340, P305 P351 P338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)	3 0 1
Related compounds
Related compounds	Sodium hydroxide
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Sodium deuteroxide or deuterated sodium hydroxide is a chemical compound with the formula Na O D or NaO²H. IUPAC recommends that the symbol for deuterium should be ²H,^[2] although most chemists use the term NaOD. It is a white solid very similar to sodium hydroxide, of which it is an isotopologue. It is used as a strong base and deuterium source in the production of other deuterated compounds. For example, reaction with chloral hydrate gives deuterated chloroform,^[3] and reaction with N-nitrosodimethylamine gives the deuterated analog of that compound.^[4]^{[full citation needed]} Sodium deuteroxide is an ionic compound, consisting of sodium cations Na and deuteroxide anions ⁻OD (or ⁻O²H).

Notes

References

^ "Sodium deuteroxide". Sigma aldrich. Retrieved 30 April 2021.
^ "Provisional Recommendations". Nomenclature of Inorganic Chemistry. Chemical Nomenclature and Structure Representation Division. IUPAC. § IR-3.3.2. Archived from the original on 27 October 2006. Retrieved 2024-08-01.
^ Breuer, F. W. (1935). "Chloroform-d (Deuteriochloroform)". Journal of the American Chemical Society. 57 (11): 2236–2237. doi:10.1021/ja01314a058.
^ National Cancer Institute (U.S.) (1973). Journal (51 ed.). the University of Michigan.

[1] "Sodium deuteroxide". Sigma aldrich. Retrieved 30 April 2021.

[2] "Provisional Recommendations". Nomenclature of Inorganic Chemistry. Chemical Nomenclature and Structure Representation Division. IUPAC. § IR-3.3.2. Archived from the original on 27 October 2006. Retrieved 2024-08-01.

[3] Breuer, F. W. (1935). "Chloroform-d (Deuteriochloroform)". Journal of the American Chemical Society. 57 (11): 2236–2237. doi:10.1021/ja01314a058.

[4] National Cancer Institute (U.S.) (1973). Journal (51 ed.). the University of Michigan.

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