Thallium trifluoride

(Redirected from Thallium(III) fluoride)

Thallium trifluoride is the inorganic compound with the formula TlF3. It is a white solid. Aside from being one of two thallium fluorides, the compound is only of theoretical interest. It adopts the same structure as bismuth trifluoride, featuring eight-coordinate Tl(III) centers.[1] Some evidence exists for a second polymorph.

Thallium trifluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.100 Edit this at Wikidata
EC Number
  • 232-010-8
UNII
  • InChI=1S/3FH.Tl/h3*1H;/q;;; 3/p-3
    Key: BOUDEKXATYHWHY-UHFFFAOYSA-K
  • [F-].[F-].[F-].[Tl 3]
Properties
F3Tl
Molar mass 261.38 g·mol−1
Appearance white solid
Density 8.65 g/cm3
Hazards
GHS labelling:
GHS06: ToxicGHS08: Health hazardGHS09: Environmental hazard
Danger
H300, H330, H373, H411
P260, P264, P270, P271, P273, P284, P301 P310, P304 P340, P310, P314, P320, P321, P330, P391, P403 P233, P405, P501
Related compounds
Other anions
Thallium(III) chloride
Other cations
Aluminum fluoride
Gallium(III) fluoride
Thallium(I) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

References

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  1. ^ Christoph Hebecker (1972). "Die Kristallstruktur von Thalliumtrifluorid (Crystal Structure of Thalliumtrifluorides)". Zeitschrift für Anorganische und Allgemeine Chemie. 393: 223–229. doi:10.1002/zaac.19723930305.223-229&rft.date=1972&rft_id=info:doi/10.1002/zaac.19723930305&rft.au=Christoph Hebecker&rfr_id=info:sid/en.wikipedia.org:Thallium trifluoride" class="Z3988">