Studtite, chemical formula [(UO2)O2(H2O)2]·2(H2O)[2] or UO4·4(H2O),[3] is a secondary uranium mineral containing peroxide formed by the alpha-radiolysis of water during formation.[5] It occurs as pale yellow to white needle-like crystals often in acicular, white sprays.
| Studtite | |
|---|---|
 | |
| General | |
| Category | Oxide mineral |
| Formula (repeating unit) | UO2O2·4(H2O) |
| IMA symbol | Stu[1] |
| Strunz classification | 4.GA.15 Uranyl hydroxides |
| Dana classification | 05.03.01.01 |
| Crystal system | Monoclinic |
| Crystal class | Prismatic (2/m) (same H-M symbol) |
| Space group | C2/m |
| Identification | |
| Color | Yellow to pale yellow; nearly colorless in transmitted light |
| Crystal habit | Needlelike crystals in radial fibrous aggregates and crusts |
| Tenacity | Flexible |
| Mohs scale hardness | 1 - 2 |
| Luster | Vitreous, waxy |
| Streak | Light yellow |
| Diaphaneity | Translucent |
| Specific gravity | 3.58 |
| Optical properties | Biaxial ( ) |
| Refractive index | nα = 1.545 nβ = 1.555 nγ = 1.680 |
| Birefringence | δ = 0.135 |
| Ultraviolet fluorescence | Non-fluorescent |
| Alters to | Dehydrates to metastudtite |
| Other characteristics |  Radioactive |
| References | [2][3][4] |
Studtite was originally described by Vaes in 1947[6] from specimens from Shinkolobwe, Katanga Copper Crescent, Katanga (Shaba), Democratic Republic of Congo, and has since been reported from several other localities. The mineral was named for Franz Edward Studt, an English prospector and geologist who was working for the Belgians.
When exposed to air studtite converts over a short time to the metastudtite UO4·2(H2O) form. Despite their apparent chemical simplicity, these two uranyl species are the only reported peroxide minerals.[5]
They may also be readily formed on the surface of nuclear waste under long-term storage and have been found on the surface of spent nuclear fuel stored at the Hanford, Washington nuclear site.[7] It has also been reported that studtite has since formed on the corium lavas that were created during the course of the Chernobyl nuclear plant accident.[7] Thus, there is considerable evidence that uranyl peroxides such as studtite and metastudtite will be important alteration phases of nuclear waste, possibly at the expense of other minerals, such as uranyl oxides and silicates, which have been more thoroughly studied and are better understood. The formation of these minerals may impact the long-term performance of deep geological repository sites such as Yucca Mountain nuclear waste repository.[7] Due to insufficient information about these minerals it is unknown if they will make radioactive wastes more or less stable, but the presence of studtite and metastudtite provides a pathway for mobilizing insoluble U(IV) from the corroding fuel surface into soluble uranyl species.[8]
References
edit- ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
- ^ a b http://webmineral.com/data/Studtite.shtml Studtite at Webmineral
- ^ a b http://rruff.geo.arizona.edu/doclib/hom/studtite.pdf Handbook of Mineralogy
- ^ http://www.mindat.org/min-3815.html Mindat.org
- ^ a b "Studtite: The first structure of a peroxide mineral" (PDF). Archived from the original (PDF) on 2011-07-13. Retrieved 2010-02-21.
- ^ Annales de la Société Géologique de Belgique - 1947 - pp B212 to B226- J.F. Vaes - Six nouveaux minéraux d'urane provenant de Shinkolobwe (Katanga) -
- ^ a b c Kubatko KA, Helean KB, Navrotsky A, Burns PC (November 2003). "Stability of Peroxide-Containing Uranyl Minerals". Science. 302 (5648): 1191–1193. doi:10.1126/science.1090259. PMID 14615533. S2CID 44415700.
- "Unusual Minerals Formed on Stored Nuclear Waste". November 21, 2003. Archived from the original on 2003-12-02.
- ^ Guo X, Ushakov SV, Labs S, Curtius H, Bosbach D, Navrotsky A (2015). "Energetics of Metastudtite and Implications for Nuclear Waste Alteration". Proc. Natl. Acad. Sci. USA. 111 (20): 17737–17742. doi:10.1073/pnas.1421144111. PMC 4273415. PMID 25422465.
