Wikipedia

Selenidogermanate

Selenidogermanates are compounds with anions with selenium bound to germanium. They are analogous with germanates, thiogermanates, and telluridogermanates.[1]

List

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name formula formula weight crystal

system

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group

cell dimensions volume density comment ref
GeSe2 [2]
Ge4Se9 orthorhombic Pca21 a 17.8204 b 7.0029 c 12.0854 [2]
Li3Ge3Se6 triclinic P1 a 6.7728 b 8.6804 c 10.6300 α 74.519° β 76.334° γ 69.185° [3]
[Li4(H2O)16][Ge4Se10]·4.33H2O monoclinic P21 a=10.2246 b=20.4503 c=28.7242 β=97.850° [4]
{Li4(thf)12}Ge4Se10 monoclinic C2/c a=24.845 b =12.692 c=25.625 β=119.00° [4]
[Li2(H2O)8][MnGe4Se10] tetragonal I4 a=9.103 c =15.130 [4]
[NH4]2[H2N(CH3)2]2Ge2Se6 monoclinic P21/n a 13.503 b 7.777 c 19.583 β 106.03° [5]
(N2H5)4Ge2Se6 tetragonal I41cd a = 12.708 c = 21.955 Z = 8 [6]
[NEt4]2[enH]2[Ge2Se6] triclinic P1 a = 7.805, b = 10.747, c = 11.445, α = 110.33°, β = 97.19°, γ = 92.62° V = 889.0 [7]
tetrakis(Tripropylammonium) hexakis(μ2-selenido)-tetrakis(selenoxo)-tetra-germanium(iv) monoclinic P21/c a 18.759 b 16.104 c 21.211 β 108.52° [8]
(C2C1Im)4[Ge4Se10] 1524.63 tetragonal P42/n a=13.675 c=12.042 Z=2 2251.9 2.249 yellowish [1]
1-Ethyl-3-methyl-imidazolium (C2C1Im)6[Ge8Se19]; 2747.96 triclinic P1 a=10.2607 b=17.6852 c=21.994 α=100.889

β= 95.600  γ=105.240 Z=2

3735.5 2.443 yellowish [1]
(C2C1Im)6[Ge8Se19] 2747.96 monoclinic P121/c1 a=22.206 b=9.544 c=36.823 β=105.37 Z=4 7524.8 2.426 yellow [1]
(C2C1Im)8[Ge16Se36] 4893.34 monoclinic C12/c1 a=20.527 b=28.744 c=19.720 β=94.640 Z=4 11597 2.803 yellow [1]
2(C2C1Im)6[Ge12Se27] 7340.01 monoclinic P121/n1 a=14.834 b=30.647 c=20.465 β=107.603 Z=2 8868 2.749 red [1]
(C4C1im) 2{[SnII(GeIV4Se10)]2−} monoclinic P21/n a 9.9685 b 26.2588 c 13.9736 β 98.766° [9]
Na2GeSe3 monoclinic P21/c a =7.097 b=16.068 c=6.073 β =113.69° Z=4 3.72 yellow [10]
Na4GeSe4 orthorhombic Pnma a = 28.518 b=9.447 c=7.128 Z=8 orange-yellow [11]
Na4[Ge4Se10] orthorhombic Cmcm a=13.507 b=13.363 c=11.034 Z=4 1881.6 [12]
Na4Ge(Se2)4 red [13]
Na6Ge2Se6 monoclinic P21 a = 8.367 b = 11.924 c = 8.158 β = 118.6° [14]
Na6Ge2Se7 monoclinic C2/c a=9.451 b=10.914 c=15.874 β=104.7° 3.51 yellow [15][16]
Na8Ge4Se10 triclinic P1 a = 7.074 b = 8.098 c = 10.657 α = 73.4° β = 70.8° γ= 81.7° [14]
Na8Ge4Se10 monoclinic P21/c a = 13.104 b=12.057 c=14.101 β= 92.9° Z=4 3.77 orange yellow [10]
[Na4(H2O)14][GeSe4] monoclinic C2 a = 12.862, b = 11.205, c = 8.141 Å, β = 107.40° [17]
Na4Ge2Se6 · 16 H2O monoclinic P21/c a = 9.894 b = 11.781 c = 12.225 β = 92.90° Z = 2 [18]
Na6Ge2Se6 · 4 CH3OH [19]
Na3GeSe3Br [20]
Mg2GeSe4 437.05 orthorhombic Pnma a 13.50 b 7.85 c 6.37 Z=4 675 4.302 yellow [21]
Li2MgGeSe4 orthorhombic Pmn21 a = 8.2961 b = 7.0069 c = 6.6116, Z = 2 384.33 3.686 yellow [22]
Na4MgGe2Se6 735.21 monoclinic C2 a 7.722 b 11.994 c 7.096 β 106.66° Z=2 629.7 3.878 orange-yellow [23]
K2GeSe4 monoclinic P21/c a=11.989 b=8.275 c=8.915 β=106.38° Z=4 848.8 3.65 orange [24]
K2Ge4Se8 monoclinic P21/c a=7.3752 b=12.239 c=17.468 β=96.102°, Z=4 1156.8 band gap 1.8 eV [25]
K4[GeSe4] cubic P43n a=13.1893 [26]
[K4(H2O)4][GeSe4] triclinic P1 a 7.8695 b 7.9576 c 12.314, α 80.24° β 87.66° γ 74.07° [26]
[K4(H2O)3][Ge2Se6] monoclinic P21/c a 14.583 b 8.3858 c 14.17 β 96.27° [26]
[K4(H2O)3][Ge4Se10] [1]
K6Ge2Se6 monoclinic C2/c a=9.076 b=12.851 c=8.480 β=116.76° [27]
[V(en)2(ea)]2[Ge2Se6] monoclinic P21/n a 8.733 b 13.432 c 13.583 β 91.486° Z=4 1592.8 2.256 red [28]
[V(teta)(ea)]2[Ge2Se6] monoclinic P21/n a 9.0574 b 14.209 c 13.1189° β 91.384° Z=4 1687.8 2.232 red [28]
[V2(en)6(μ-O)][Ge2Se6] triclinic P1 a 9.448 b 10.178 c 10.436 α 109.090° β 104.169° γ 111.520° Z=1 802.7 2.271 brown [28]
Na2MnGe2Se6 1439.72 tetragonal I4/mcm a = 7.772 c = 19.077 Z = 2 1152.3 4.150 @153K band gap 1.93 eV; brown [29]
Na8Mn2(Ge2Se6)2 monoclinic C2 a 7.727 b 11.943 c 7.085 β 106.682° band gap 1.95 eV [30]
K2MnGe2Se6 tetragonal I4/mcm a =8.1315 c =18.877 [31]
[Mn(en)3]2Ge2Se6 monoclinic P21/n a 9.058 b 16.319 c 11.628 β 92.264° [32]
(enH2)[{Mn(en)2(enH)}2(μ-en)](Ge2Se7)2 orthorhombic Pbca a 15.816 b 13.638 c 24.677 [33]
[Mn(dien)2]2Ge2Se7 monoclinic P21/c a 16.489 b 14.524 c 15.860 β 101.03° [33]
[{Mn(tepa)}2(μ-Ge2Se6)] tetragonal I 41/a a=26.387 c 9.9435 [34]
[K2(H2O)3][MnGe4Se10] tetragonal I4 a=8.988 c=15.49 [35]
Bis(trimethylammonium) decaselenidotetragermanatomanganate(II) [(CH3)3NH]2[MnGe4Se10] tetragonal I4 a 9.559 c 14.808 [36]
[Fe(dien)2]2Ge2Se6 monoclinic P21/n a 12.426 b 9.312 c 15.385 β 101.422° [32]
[{Fe(tepa)}2(μ-Ge2Se6)] tetragonal I 41/a a 26.285 c 9.882 [34]
K2FeGe3Se8 monoclinic P21 a 7.409 b 12.268 c 34.974 β 96.04° band gap 1.95 eV [37]
[Ni(dien)2]2Ge2Se5(Se2) monoclinic P21/c a 15.741 b 14.463 c 16.390 β 103.03° [5]
[{Ni(tepa)}2(μ-Ge2Se6)] tetragonal I41/a a=26.001 c=9.708 [5]
triethylenetetramine [Ni(teta)2]2Ge4Se10·0.5H2O monoclinic P21/c a 21.202 b 13.345 c 20.872 β 107.46° [38]
(enH2)5[Cu16Ge6Se19(Se2)6]·en cubic Pa3 a=a 20.8113 Z=12 [39]
[(CH3)2NH2]6[Cu8Ge6Se19]·0.25H2O Im3 a=22.43070 [39]
[NH3CH3]0.75Cu1.25GeSe3 tetragonal P421m a=12.9345 c 8.9057 [40]
decakis(1-ethyl-3-methyl-1H-imidazol-3-ium) hexakis(μ-cyanido)-nonatriacontakis(μ-selenido)-selenido-hepta-copper(i)-hexadeca-germanium(iv)-penta-sodium (C2C1Im)10[Na5(CN)6@Cu6(Ge4Se10)4(Cu)] triclinic P1 a 19.2790 b 20.4268 c 23.2357 α 105.275° β 93.657° γ 115.206° Z=2 7822.6 2.610 red [41]
decakis(1-ethyl-3-methyl-1H-imidazol-3-ium) hexakis(μ-cyanido)-nonatriacontakis(μ-selenido)-selenido-hepta-copper(i)-hexadeca-germanium(iv)-penta-sodium (C2C1Im)10[Na5(CN)6@Cu6(Ge4Se10)4(Cu)] 6147.36 triclinic P1 a 20.3454 b 20.8202 c 23.120 α 72.172° β 68.184° γ 60.802° Z=2 7842.1 2.472 red [41]
1,2-dap = 1,2-diaminopropane [Mn(1,2-dap)2][Cu2GeSe5] monoclinic P21/c a 6.673 b 18.210 c 15.070 β 96.078° [42]
[Cu2GeSe5][Mn(Hen)2(en)] monoclinic P21/c a 9.6327 b 20.6934 c 10.3704 β 100.646° band gap 1.69 eV [43]
tren = tris(2-aminoethyl)amine [Ni(tren)(en)]2∙[Cu2GeSe5]2 orthorhombic P212121 a 9.8574 b 13.0311 c 32.77 [42]
[Ni(dien)2]2Ge2Se5(Se2) monoclinic P21/c a=15.741 b=14.463 c=16.390 β=103.03(3)° [5]
{Ni(tepa)}2(μ-Ge2Se6) tetragonal I41/a a=26.001 c=9.7079 [5]
[NH3CH3]0.75Cu1.25GeSe3 tetragonal P421m a 12.9345 c 8.9057 [40]
Na2ZnGe2Se6 tetragonal I4/mcm a 7.757 c 18.734 band gap 2.36 eV [44][45]
Cu2ZnGeSe4 tetragonal I4 band gap 1.38; air stable; SHG 43 pm/V at λ = 2900 nm [46]
Cu4ZnGe2Se7 monoclinic C2 a 12.3443 b 5.6195 c 8.7904 β 98.693° band gap 0.91 eV; air stable [46]
N-(2-aminoethyl)piperazine (H2NC4H8NCH2CH2NH2)(HNCH2CH2NH2)3Zn2Ge2Se8 orthorhombic P21212 a=18.928 b=30.849 c=6.3954 [47]
[NH4]2Ga4Se8Ge4 monoclinic P21/c [48]
NaGaGe3Se8 monoclinic P21/c a 7.233 b 11.889 c 17.550 β 101.75° Z=4 1477.5 4.235 orange [49]
K2Ga2Ge2Se8 monoclinic P21/c a 7.3552 b 12.4151 c 17.6213 β 97.026° Z=4 1597.02 4.136 yellow [50]
K3Ga3Ge7Se20 2413.79 monoclinic P21/c a 7.0520 b 39.033 c 6.9488 β 90.433° Z=2 1912.67 4.191 orange [49]
K3Ga3(Ge4.95Si2.05)Se20 monoclinic Pc a 7.0101 b 38.928 c 6.9863 β 90.531° [51]
Rb2GeSe4 559.4 monoclinic P2/m a=7.390 b=3.704 c=8.623 β=104.87 Z=1 228.1 4.07 orange-brown [24]
Rb4Ge4Se10 monoclinic C2/c a = 16.095 b = 16.09 c = 9.390 β= 105.79° [52]
Rb4Ge4Se12 orthorhombic Pna21 a 14.870 b 13.800 c 12.445 Z=4 2554 4.109 red [53]
Rb4Ge4Se10 • CH3OH 1453.9 monoclinc C2 a=17.099 b=9.287 c=9.503 β=118.49 Z=2 1326.3 3.64 yellow [24]
Rb2MnGe3Se8 orthorhombic P212121 a 7.2756 b 12.1668 c 16.8351 [54]
Rb2[MnGe4Se10]·3H2O tetragonal [55]
Rb3(AlSe2)3(GeSe2)7 monoclinic P21/c a = 7.0580 b = 39.419 c = 7.0412 β = 90.360° Z = 2 #190K; band gap 2.4 eV [56]
RbGaGeSe4 orthorhombic Pnma a=17.5750 b= 7.4718 c= 12.4449 Z=8 1634.23 4.419 colourless; air sensitive [50]
γ-Sr2GeSe4 orthorhombic Ama2 a = 10.284 b = 10.543 c = 7.411 Z=4 [57][58]
Strontium Selenogermanate(III) Sr2Ge2Se5 monoclinic P21/n a=8.445 b=12.302 c=9.179 β=93.75° Z=4 Ge-Ge bond [59]
tepa=tetraethylenepentamine (H2peha)[Y2(μ-OH)2(tepa)2Cl2]{[Y2(μ-OH)2(tepa)2Cl]2(μ-Ge2Se6)}[Ge2Se6]Cl2 triclinic P1 a 9.1861 b 17.3698 c 19.5422 α 103.218° β 95.414° γ 101.439° [60]
Y2(tepa)2(μ-OH)2(μ-Ge2Se6)]·H2O monoclinic C2/c a 21.87 b 12.245 c 18.724 β 127.58° [61]
AgxNa(6-x)Ge2Se7 x=1.76 [62]
AgxNa(8-x)Ge4Se10 C2/c [62]
K2Ag2GeSe4 orthorhombic Fddd a 6.613 b 13.776 c 21.822 [63]
Ag2FeGeSe4 orthorhombic [64]
AgGaGeSe4 tetragonal I42d a = 5.8056 c = 10.349 348.81 band gap 2.27 eV [65]
Rb2Ag2GeSe4 1579.76 orthorhombic Fddd a 6.8633 b 13.9740 c 22.627 [66]
RbAg3Ga8Se14 monoclinic Cm a 12.9155 b 11.7376 c 9.6693 β 116.367° [67]
Ag2Sr3Ge2Se8 cubic I43d [68]
Rb3[AgGe4Se10]·2H2O [55]
Li7Cd4.5Ge4Se16 orthorhombic Pna21 a 14.165 b 8.2990 c 6.6869 band gap 2.18 eV; melt 985K [69]
Na2CdGe2Se6 monoclinic Cc a 7.589 b 13.182 c 12.069 β 98.829° SHG 2×AgGaS2 at 2.09 μm [44]
K2CdGe3Se8 1040.05 monoclinic P21 a=7.6069 b=12.4016 c=17.6585 β=95.306° Z=4 1658.71 4.165 brownish yellow [70]
SrCdGeSe4 orthorhombic Ama2 a = 10.8245 b = 10.6912 c = 6.6792 Z=4 red; band gap 1.9 eV; melt 851; SHG 5× AgGaS2 [71]
[NH4]2In4Se8Ge4 monoclinic P21/c a 7.642 b 12.470 c 18.222 β 95.214° [48]
KInGeSe4 monoclinic P21/c a=7.6108 b=12.4473 c=18.0896 β=97.238° Z=8 1700.0 4.239 yellow [72]
RbInGeSe4 orthorhombic Pnma a=17.9948 b=7.6908 c=12.6003 Z=8 1743.8 4.475 yellow [72]
K3Ga3(Ge6.17Sn0.83)Se20 monoclinic Pc a 7.0843 b 39.404 c 7.0212 β 90.567° [51]
Na9Sb(Ge2Se6)2 monoclinic C2/c a = 8.95 b = 24.33 c = 7.066 β = 122.10° Z=2 1303 3.992 red [73]
Sr3GeSb2Se8 orthorhombic Pnma a = 12.633 b = 4.301 c = 28.693 Z = 4 1558.8 band gap 0.75 eV [74]
Cs4Ge2Se6 monoclinic P21/n a 7.6295 b 9.6884 c 19.773 β=98.78° [75]
Cs4Ge2Se8 1308.5 monoclinic C2 a=17.503 b=9.549 c=9.751 β=118.16° Z=2 1436.8 3.87 orange-yellow [76]
Cs4Ge4Se10 monoclinic C2/c a = 16.348 b = 16.49 c = 9.771 β = 107.10° [52]
Cs4Ge4Se10 · 2CH3OH 1675.7 monoclinic C2/m a=15.278 b=7.624 c=10.090 β=121.71° Z=2 999.8 4.34 yellow [76]
Cs4Ge4Se12 1769.52 orthorhombic Pna21 a 15.193 b 13.944 c 12.845 Z=4 2721.4 4.319 red [53]
(C4C1C1im) 7{[Cs@SnII4(GeIV4Se10)4]7−} cubic P43m a=15.446 Cs in a tetrahedron [9]
heptakis(1-ethyl-3-methyl-1H-imidazol-3-ium) hexatriacontakis(μ-selenido)-tetraselenido-cesium-tetra-germanium(ii)-hexadeca-germanium(iv) (C2C1Im)7[Cs@GeII4(GeIV4Se10)4] 4831.2 orthorhombic P212121 a 18.1595 b 18.5017 c 36.632 Z=4 12307.8 2.980 yellow [41]
Cs2MgGe3Se8 orthorhombic P212121 a 7.6635 b 12.7242 c 17.7724 [77]
Cs[Cr(en)2GeSe4] 693.57 monoclinic P21/n a=11.3115 b=12.3519 c=11.4514 β =93.359 Z=4 1597.2 2.884 black [78]
Cs2MnGe3Se8 orthorhombic P212121 a 7.6376 b 12.648 c 17.762 [54]
Cs2[MnGe4Se10]·3H2O tetragonal [55]
Cs2Cu2GeSe4 monoclinic C2/c a 7.8231 b 23.953 c 6.0197 β 113.75° [66]
Cs2ZnGe3Se8 orthorhombic P212121 a 7.5756 b 12.6191 c 17.6543 [77]
CsGaGeSe4 orthorhombic Pnma a= 17.7666 b= 7.5171 c= 12.6383 Z=8 1687.9 4.652 colourless [50]
Cs2Ge3Ga6Se14 P3m1 a = 7.6396 c =13.5866 Z = 1 686.72 dark red [79]
(Cs6Cl)2Cs5[Ga15Ge9Se48] tetragonal I4/m a 14.3870 c 28.012 [80]
[Cs6Cl][Ga5GeQ12] band gap 2.89 eV; porous layers [81]
(Cs6Br)2Cs5[Ga15Ge9Se48] tetragonal I4/m a 14.3806 c 27.934 [80]
(Cs6I0.6Cl0.5)2Cs5[Ga15Ge9Se48] tetragonal I4/m a 14.4267 c 28.082 [80]
(Cs5KCl)2Cs5[Ga15Ge9Se48] tetragonal I4/m a=14.3309 c=27.797 [80]
(Rb6Cl)2Cs5[Ga15Ge9Se48] tetragonal I4/m a=14.2193 c=27.410 Z=2 5542 [80]
(Rb6Br)2Cs5[Ga15Ge9Se48] tetragonal I4/m a=14.4034 c=27.598 Z=2 5646.3 [80]
Cs3AsGeSe5 monoclinic C2/m a 14.252 b 7.4 c 10.335 β 124.07° [75]
CsAg3Ga8Se14 monoclinic Cm a 12.9694 b 11.7931 c 9.7011 β 116.805° [67]
Cs3[AgGe4Se10]·2H2O [55]
Cs2CdGe3Se8 orthorhombic P212121 7.7048 b 12.6822 c 17.8208 [77]
Cs2Ge3In6Se14 R3m a = 7.9951 c = 41.726 band gap 2.08 eV [82]
Ba2Ge2Se5 orthorhombic Pnma a=12.863 b=9.174 c=9.160 Z=4 [59]
[Ba2(H2O)9][GeSe4] 825.25 orthorhombic Pbca a 13.916 b 15.097 c 16.116 Z=8 3385.9 3.238 light yellow [83]
Ba6Ge2Se12 monoclinic P21/c a = 10.0903 b = 9.3640 c = 25.7643 β = 90.303° [84]
Ba7Ge2Se17 orthorhombic Pnma a = 12.652 b = 20.069 c = 12.3067 [84]
Ba4Ge3Se9Cl2 P63 a 10.0924 b 10.0924 c 12.512 [85]
Ba3[Mn6Ge4Se17]·19H2O 2716.66 triclinic P1 a 12.184 b 15.089 c 15.868 α 88.73° β 73.68° γ 71.06° Z=2 2640.4 3.412 red [83]
Ba3[Mn6Ge4Se17]·30H2O rhombohedral R3c a 20.463 c 25.11 Z=6 9109 3.188 orange-red [83]
BaCu2GeSe4 P3121 a 6.5014 c 16.266 red [86]
BaZnGeSe4 orthorhombic Ama2 a = 11.3255 b = 11.2527 c = 6.2917 band gap 2.46 eV [87]
LiBa4Ga5Se12 orthorhombic P421c a 13.0056 b 13.0056 c 6.2671 band gap 2.44 eV [88]
Ba4Ge3Se9Br2 hexagonal P63 a = 10.2345 c = 12.5306
BaCdGeSe4 orthorhombic Fdd2 a=22.167 b=22.768 c=13.303 band gap 1.67 eV; SHG 0.5 × AgGaS2 [89]
Ba4GeSb2Se11 1734.01 orthorhombic Cmc21 a = 9.37 b = 25.85, c = 8.80 Z=4 2131 5.404 [90]
La4Ge3Se2S10 rhombohedral R3c a=19.5575 c=8.1468 2698.6 4.605 Yellow-orange [91]
La4Ge3Se4S8 rhombohedral R3c 2745.3 Yellow-orange [91]
La4Ge3Se6S6 rhombohedral R3c 2792.6 orange [91]
La4Ge3Se8S4 rhombohedral R3c 2845.3 red [91]
La4Ge3Se10S2 rhombohedral R3c 2912.1 red [91]
lanthanum(III) bis[hexaselenodigermanate] Na9La[Ge2Se6]2 monoclinic C12/m1 a =7.974 b=12.337 c=7.114 β=107.101° Ζ=1 669.0 orange [92]
Ba4LaSbGe3Se13 monoclinic P21/c a=16.3330 b=12.5115 c=13.0321 β=103.457° Z=4 2590.0 red; band gap 2.0 eV [93]
[Ce4(tepa)4(μ-GeSe4)(μ-GeSe5)(μ-Ge2Se6) triclinic P1 a 12.273 b 16.624 c 18.281 α 91.264° β 101.034° γ 96.497° [60]
KCeGeSe4 monoclinic P21 a = 6.852 b = 7.025 c = 9.017 β = 108.116° Z = 2 [94]
Pr(teta)(tren)Cl]2[Ge2Se6](en) triclinic P1 a 10.3153 b 10.4707 c 14.0511 α 99.606° β 92.679° γ 119.146° [95]
Nd(teta)(tren)Cl]2[Ge2Se6](en) triclinic P1 a 10.2840 b 10.4774 c 14.0341 α 99.655° β 92.651° γ 119.161° [95]
Na9Sm(Ge2Se6)2 monoclinic C2/m a = 7.916 b = 12.244 c = 7.105 β = 106.99° Z = 1 658.6 [96][97]
Sm2(μ-OH)2(tepa)2(μ-Ge2Se6) monoclinic P21/n a 12.10 b 11.41 c 12.71 β 92.81° [60]
Sm(teta)(tren)Cl]2[Ge2Se6](en) triclinic P1 a 10.3327 b 10.482 c 14.003 α 77.816° β 87.499° γ 60.62° [95]
NaSmGeSe4·0.25Na2Se monoclinic C2/c a 22.508 b 11.0307 c 6.8261 β 103.038° [98]
KSmGeSe4 monoclinic P21 a = 6.774 b = 6.994 c = 8.960 β = 108.225° Z = 2 403.2 [99]
RbSmGeSe4 orthorhombic P212121 a = 6.7347 b = 7.0185 c = 17.723 Z=4 837.7 [99]
CsSmGeSe orthorhombic P212121 a=6.707 b=7.067 c=18.334 Z=4 869.1 [99]
Eu2GeSe4 monoclinic P21 a = 6.964 b = 7.055 c = 8.400 β = 108.12° Z = 2 deep red [100]
Eu2GeSe4 monoclinic P21/m a = 6.969 b = 7.059 c = 8.516 β = 107.99° Z = 2 @673K [100]
Eu2Ge2Se5 monoclinic P21/n a = 8.421 b = 12.235 c = 9.127 β = 93.67° Z = 4 deep red [100]
{Eu(en)3}2(μ-OH)2]Ge2Se6 monoclinic P21/n a 10.062 b 11.538 c 15.227 β 98.470° [101]
Eu(teta)(tren)Cl]2[Ge2Se6](en) triclinic P1 a 10.364 b 10.549 c 14.1157 α 77.299° β 87.606° γ 60.697° [95]
{Eu(tepa)(μ-OH)}2(μ-Ge2Se8) monoclinic P21/n a 12.384 b 11.697 c 12.965 β 94.107° [102]
Na2EuGeSe4 cubic I43m a=7.3466 Z=2 [103]
Na0.75Eu1.625GeSe4 cubic I43d a=14.7065 Z=16 [103]
K2EuGeSe5 monoclinic P21/c a = 11.8056 b = 9.9630 c = 8.9456 β = 91.195° Z = 4 1051.9 4.404 @167K; band gap 1.84 eV; Eu(II) [104]
EuCdGeSe4 orthorhombic Ama2 a 10.7525 b 10.6275 c 6.6740 Z=4 762.6 5.685 red; band gap 2.25 eV; SHG 3.8 × AgGaS2 [105]
Gd(teta)(tren)Cl]2[Ge2Se6](en) triclinic P1 a 10.310 b 10.495 c 14.055 α 77.50° β 87.51° γ 60.81° [95]
{Gd(tepa)(μ-OH)}2(μ-Ge2Se8) monoclinic P21/n a 12.316 b 11.667 c 12.868 β 93.70° [102]
{Dy(tepa)(μ-OH)}2(μ-Ge2Se8) monoclinic P21/n a 12.329 b 11.627 c 12.882 β 94.177° [102]
[{Dy(en)3}2(μ-OH)2]Ge2Se6 a 10.026 b 11.526 c 15.147 β 99.030° [102]
Tb2(tepa)2(μ-OH)2(μ-Ge2Se8) monoclinic P21/n a 12.228 b 11.587 c 12.782 β 93.458° [61]
Tb(teta)(tren)Cl]2[Ge2Se6](en) triclinic P1 a 10.2303 b 10.4499 c 14.0083 α 99.655° β 92.737° γ 119.069° [95]
[Tb2(tepa)2(μ-OH)2(μ-Ge2Se6)]·0.5H2O monoclinic C2/c a 22.007 b 12.3363 c 18.2590 β 125.196° [106]
[{Ho(en)3}2(μ-OH)2]Ge2Se6 monoclinic P21/n a 9.997 b 11.550 c 15.109 β 99.289° [101]
[{Ho(dien)2}2(μ-OH)2]Ge2Se6 monoclinic P21/n a 11.920 b 11.583 c 13.691 β 98.154° [101]
Ho2(μ-OH)2(tepa)2(μ-Ge2Se6) orthorhombic Pbca a 12.1791 b 13.487 c 20.346 [60]
(H2peha)[Er2(μ-OH)2(tepa)2Cl2]{[Er2(μ-OH)2(tepa)2Cl]2(μ-Ge2Se6)}[Ge2Se6]Cl2 triclinic P1 a 9.1544 b 17.382 c 19.443, α 102.994° β 95.306° γ 101.406° [60]
(H3O)[Tm(teta)2][Ge2Se6] orthorhombic Pccn a 13.7846 b 14.3998 c 17.9221 [95]
Tm2(tepa)2(μ-OH)2(μ-Ge2Se6) orthorhombic Pbca a 12.1702 b 13.528 c 20.281 [106]
Li2HgGeSe4 602.90 orthorhombic Pna21 a=14.150 b=8.260 c=6.692 Z=4 782.2 5.119 yellow [107]
Na2Hg3Ge2Se8 1424.61 tetragonal P4c2 a=9.1938 c=9.5437 Z=2 806.69 5.865 red [107]
SrHgGeSe4 orthorhombic Ama2 a 10.8375 b 10.7456 c 6.6377 NLO 5 × AgGaS2 [108]
BaHgGeSe4 orthorhombic Ama2 a 11.255 b 11.033 c 6.685 NLO 5 × AgGaS2 [108]
EuHgGeSe4 orthorhombic Ama2 a 10.6530 b 10.5990 c 6.5986 band gap; SHG 3.1 × AgGaS2 [109]
TlGaGeSe4 orthorhombic Pnma a= 17.4742 b= 7.4105 c= 11.9406 Z=8 1546.22 5.692 red [50]
Tl2Ga2GeSe6 tetragonal I4/mmc a = 8.0770 c = 6.2572 Z = 4 [110]
TlInGeSe4 702 monoclinic P21/c a= 7.586 b= 12.134 c=18.023 β= 96.037° Z=8 1649.8 5.653 yellow [72]
TlInGe2Se6 trigonal R3 a = 10.1798 c = 9.2872 band gap 2.38 eV [111]
α-Pb2GeSe4 [57]
Na0.5Pb1.75GeSe4 cubic I43d a = 14.662 [97]
PbGa2GeSe6 melt 687 °C; phase transition 522 °C [112]
Pb4Ga4GeSe12 [112]
Pb3Ga2GeSe8 P421c melt incongruently 656 °C [112]
Sr1.31Pb0.69GeSe4 orthorhombic Ama2 a = 10.31220 b = 10.39320 c = 7.42140 [57]
Sr0.19Pb1.81GeSe4 I42d a = 14.6177 [57]
Sr12.6Pb6.4Ge11Se44 hexagonal P63 a = 19.9867 c = 12.0546 4170.28 black; band gap 1.8 eV [113]
Ag0.5Pb1.75GeS3Se band gap 2.0 eV [114]

References

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  1. ^ a b c d e f g Wu, Zhou; Nußbruch, Isabell; Nier, Simon; Dehnen, Stefanie (23 December 2021). "Ionothermal Access to Defined Oligomers of Supertetrahedral Selenido Germanate Clusters". JACS Au. 2 (1): 204–213. doi:10.1021/jacsau.1c00473. PMC 8790736. PMID 35098237.
  2. ^ a b Fjellvåg, Helmer; Kongshaug, Kjell Ove; Stølen, Svein (2001). "Crystal structure of Ge4Se9: a new germanium selenide with Se2 pairs breaking the edge-sharing GeSe4 tetrahedra in GeSe2". Journal of the Chemical Society, Dalton Transactions (7): 1043–1045. doi:10.1039/b009794m.
  3. ^ Li, Guangmao; Zhen, Ni; Chu, Yu; Zhou, Zhongxiang (2017). "Li 3 Ge 3 Se 6 : the first ternary lithium germanium selenide with interesting ∞ [Ge 6 Se 12 ] n chains constructed by ethane-like [Ge 2 Se 6 ] 6− clusters". Dalton Transactions. 46 (47): 16399–16403. doi:10.1039/C7DT03781C. ISSN 1477-9226. PMID 29134215.
  4. ^ a b c Duchardt, Marc; Haddadpour, Sima; Kaib, Thomas; Bron, Philipp; Roling, Bernhard; Dehnen, Stefanie (2021-04-05). "Different Chemical Environments of [Ge 4 Se 10 ] 4– in the Li Compounds [Li 4 (H 2 O) 16 ][Ge 4 Se 10 ]·4.33H 2 O, [{Li 4 (thf) 12 }Ge 4 Se 10 ], and [Li 2 (H 2 O) 8 ][MnGe 4 Se 10 ], and Ionic Conductivity of Underlying "Li 4 Ge 4 Se 10 "". Inorganic Chemistry. 60 (7): 5224–5231. doi:10.1021/acs.inorgchem.1c00225. ISSN 0020-1669. PMID 33764781. S2CID 232366801.
  5. ^ a b c d e Liu, Shuzhen; Sun, Peipei; Han, Jingyu; Liu, Yun; Shen, Yali; Tang, Chunying; Sun, Hui; Jia, Dingxian (February 2017). "Solvothermal syntheses, crystal structures, optical and thermal properties of new selenidogermanate and polyselenidogermanate". Journal of Chemical Sciences. 129 (2): 167–175. doi:10.1007/s12039-017-1224-3. ISSN 0974-3626. S2CID 99258976.
  6. ^ Mitzi, David B. (2005-05-01). "Synthesis, Structure, and Thermal Properties of Soluble Hydrazinium Germanium(IV) and Tin(IV) Selenide Salts". Inorganic Chemistry. 44 (10): 3755–3761. doi:10.1021/ic048276l. ISSN 0020-1669. PMID 15877460.
  7. ^ Park, Chang-Woo; Pell, Michael A.; Ibers, James A. (1996-01-01). "Electrochemical Synthesis of [NEt 4 ] 2 [enH] 2 [Ge 2 Se 6 ] and [NEt 4 ] 4 [Sn 4 Se 10 ]". Inorganic Chemistry. 35 (16): 4555–4558. doi:10.1021/ic9514859. ISSN 0020-1669.
  8. ^ Blachnik, R.; Fehlker, A. (2000-01-01). "Crystal structure of tetrakis(tripropylammonium) decaselenidotetragermanate(IV), [C9H21NH]4[Ge4Se10]". Zeitschrift für Kristallographie - New Crystal Structures. 215 (1): 95–97. doi:10.1515/ncrs-2000-0150. ISSN 2197-4578. S2CID 95268481.
  9. ^ a b {{Cite journal |last1=Santner |first1=Silke |last2=Wolff |first2=Alexander |last3=Ruck |first3=Michael |last4=Dehnen |first4=Stefanie |date=2018-08-14 |title=Multi-Valent Group 14 Chalcogenide Architectures from Ionic Liquids: 0D-{[Cs@Sn II 4 (Ge IV 4 Se 10 ) 4 ] 7− } and 2D-{[Sn II (Ge IV 4 Se 10 )] 2− } |url=https://onlinelibrary.wiley.com/doi/10.1002/chem.201802199 |journal=Chemistry: A European Journal|language=en |volume=24 |issue=46 |pages=11899–11903 |doi=10.1002/chem.201802199 |pmid=29806888 |s2cid=44064145 |issn=0947-6539}}
  10. ^ a b Eisenmann, Brigitte; Hansa, Jendy; Schafer, Herbert (1985-04-01). "Zur Kenntnis der Selenidosilikate und -germanate Na 4 Si 4 Se 10 , Na 2 GeSe 3 und Na 8 Ge 4 Se 10 / On the Selenidosilicates and Germanates Na 4 Si 4 Se 10 , Na 2 GeSe 3 and Na 8 Ge 4 Se 10". Zeitschrift für Naturforschung B. 40 (4): 450–457. doi:10.1515/znb-1985-0402. ISSN 1865-7117. S2CID 97026108.
  11. ^ Klepp, Kurt O. (1985-07-01). "Darstellung und Kristallstruktur von Na 4 GeSe 4 : Ein neues ortho-Selenogermanat(IV)". Zeitschrift für Naturforschung B. 40 (7): 878–882. doi:10.1515/znb-1985-0705. ISSN 1865-7117. S2CID 98125379.
  12. ^ Eisenmann, B.; Hansa, J. (1993-02-01). Eisenmann, B.; Hansa, J. (eds.). "Crystal structure of tetrasodium decaselenotetragermanate, Na 4 [Ge 4 Se 10 ]". Zeitschrift für Kristallographie - Crystalline Materials. 205 (2): 325–326. Bibcode:1993ZK....205..325E. doi:10.1524/zkri.1993.205.Part-2.325. ISSN 2194-4946. S2CID 101618869.
  13. ^ Feltz, A.; Pfaff, G. (January 1985). "Glass formation and properties of chalcogenide systems XXXIV. Na4Ge(Se2)4 as a model compound for the short range order of vitreous GeSe4". Journal of Non-Crystalline Solids. 69 (2–3): 425–428. Bibcode:1985JNCS...69..425F. doi:10.1016/0022-3093(85)90044-4.
  14. ^ a b Eisenmann, B.; Hansa, J.; Schäfer, u.H. (November 1985). "Oligoselenidogermanate (III): Zur kenntnis von Na6Ge2Se6 und Na8Ge4Se10". Materials Research Bulletin (in German). 20 (11): 1339–1346. doi:10.1016/0025-5408(85)90127-8.
  15. ^ EISENMANN, B; HANSA, J.; SCHÄFER, H. (1986). "Na6Ge2Se7, das erste selenidogermanat(IV)". Na6Ge2Se7, das Erste Selenidogermanat(IV). 23 (1): 8–13. ISSN 0035-1032.
  16. ^ Villars, Pierre; Cenzual, Karin; Gladyshevskii, Roman (2017-07-24). Handbook of Inorganic Substances 2017. Walter de Gruyter GmbH & Co KG. ISBN 978-3-11-043655-6.
  17. ^ Krebs, B.; Jacobsen, H.-J. (March 1976). "Darstellung und Struktur von Na4GeSe4 • 14H2O". Zeitschrift für anorganische und allgemeine Chemie (in German). 421 (2): 97–104. doi:10.1002/zaac.19764210202. ISSN 0044-2313.
  18. ^ Krebs, Bernt; Müller, Herbert (January 1983). "Selenogermanate aus wäßriger Lösung: Darstellung und Struktur von Na4Ge2Se6 · 16 H2O". Zeitschrift für anorganische und allgemeine Chemie (in German). 496 (1): 47–57. doi:10.1002/zaac.19834960106. ISSN 0044-2313.
  19. ^ Feltz, A.; Pfaff, G. (July 1978). "Über Glasbildung und Eigenschaften von Chalkogenidsystemen. XIII. Über die Verbindungen Na6Ge2S6 · 4 CH3OH und Na6Ge2Se6 · 4 CH3OH". Zeitschrift für anorganische und allgemeine Chemie (in German). 442 (1): 41–48. doi:10.1002/zaac.19784420106. ISSN 0044-2313.
  20. ^ Feltz, A.; Pfaff, Gerhard (August 1980). "Über Glasbildung und Eigenschaften von Chalkogenidsystemen. XXI [1]. Über Na3GeS3Br und Na3GeSe3Br und die amorphen Verbindungen Ge2S3 und Ge2Se3". Zeitschrift für anorganische und allgemeine Chemie (in German). 467 (1): 211–217. doi:10.1002/zaac.19804670124. ISSN 0044-2313.
  21. ^ Wu, Kui; Su, Xin; Yang, Zhihua; Pan, Shilie (2015). "An investigation of new infrared nonlinear optical material: BaCdSnSe 4 , and three new related centrosymmetric compounds: Ba 2 SnSe 4 , Mg 2 GeSe 4 , and Ba 2 Ge 2 S 6". Dalton Transactions. 44 (46): 19856–19864. doi:10.1039/C5DT03215F. ISSN 1477-9226. PMID 26509847.
  22. ^ Gao, Hongbo; Zhang, Kewang; Abudurusuli, Ailijiang; Bai, Chen; Yang, Zhihua; Lai, Kangrong; Li, Junjie; Pan, Shilie (2021-10-18). "Syntheses, Structures and Properties of Alkali and Alkaline Earth Metal Diamond-Like Compounds Li2MgMSe4 (M = Ge, Sn)". Materials. 14 (20): 6166. Bibcode:2021Mate...14.6166G. doi:10.3390/ma14206166. ISSN 1996-1944. PMC 8537313. PMID 34683761.
  23. ^ Wu, Kui; Yang, Zhihua; Pan, Shilie (2015-11-02). "Na 4 MgM 2 Se 6 (M = Si, Ge): The First Noncentrosymmetric Compounds with Special Ethane-like [M 2 Se 6 ] 6– Units Exhibiting Large Laser-Damage Thresholds". Inorganic Chemistry. 54 (21): 10108–10110. doi:10.1021/acs.inorgchem.5b01859. ISSN 0020-1669. PMID 26484949.
  24. ^ a b c Sheldrick, W. S.; Schaaf, B. (1995-10-01). "Methanolothermale Synthese und Kristallstruktur von Diselenido- und Ditelluridogermanaten(IV) der Alkalimetalle K – Cs / M ethanolothermal Synthesis and Crystal Structure of Diselenido- and Ditelluridogerm anates(IV) of the Alkali Metals K – Cs". Zeitschrift für Naturforschung B. 50 (10): 1469–1475. doi:10.1515/znb-1995-1007. ISSN 1865-7117. S2CID 97624411.
  25. ^ Gui-Hua, Wang; Yong-Ge, W. E. I.; Gui-Ming, S. H. U.; Li-Dan, Zhang; Hong-You, G. U. O.; Ping, Wang (2004-01-28). "Solid State Synthesis, Crystal Structure and Reflectance Spectra of K2Ge4Se8". Acta Chimica Sinica. 62 (2): 165. ISSN 0567-7351.
  26. ^ a b c Melullis, Maike; Dehnen, Stefanie (October 2007). "Syntheses, Crystal Structures, UV-Vis Spectra and First NMR Spectra of New Potassium Salts of Chalcogenogermanates". Zeitschrift für anorganische und allgemeine Chemie (in German). 633 (13–14): 2159–2167. doi:10.1002/zaac.200700311.
  27. ^ B., Eisenmann; E., Kieselbach; H., Schaefer; H., Schrod (1984). "On thio-, selenido-, and telluridogermanates(III): K6Ge2S6, K6Ge2Se6, and Na6Ge2Te6". Zeitschrift für anorganische und allgemeine Chemie (in German). 516 p. 49-54. ISSN 0044-2313.
  28. ^ a b c Luo, Hai-Ying; Zhou, Jian; Cao, Shumei (2019). "A series of new hybrid chalcogenogermanates: the rare examples of chalcogenogermanates combined with trivalent vanadium complexes". Dalton Transactions. 48 (29): 10907–10914. doi:10.1039/C9DT02077B. ISSN 1477-9226. PMID 31282904. S2CID 195828996.
  29. ^ Zhou, Molin; Yin, Wenlong; Liang, Fei; Mar, Arthur; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2016). "Na 2 MnGe 2 Se 6 : a new Mn-based antiferromagnetic chalcogenide with large Mn⋯Mn separation". Journal of Materials Chemistry C. 4 (46): 10812–10819. doi:10.1039/C6TC03825E. ISSN 2050-7526.
  30. ^ Balijapelly, Srikanth; Craig, Andrew J.; Bin Cho, Jeong; Jang, Joon I.; Ghosh, Kartik; Aitken, Jennifer A.; Chernatynskiy, Aleksandr V.; Choudhury, Amitava (April 2022). "Building-block approach to the discovery of Na8Mn2(Ge2Se6)2: A polar chalcogenide exhibiting promising harmonic generation signals with a high laser-induced damage threshold". Journal of Alloys and Compounds. 900: 163392. doi:10.1016/j.jallcom.2021.163392. S2CID 245466958.
  31. ^ Li, Zhuang; Liu, Youquan; Zhang, Shengzi; Xing, Wenhao; Yin, Wenlong; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2020-06-01). "Functional Chalcogenide Na 2 HgSn 2 Se 6 and K 2 MnGe 2 Se 6 Exhibiting Flexible Chain Structure and Intriguing Birefringence Tunability". Inorganic Chemistry. 59 (11): 7614–7621. doi:10.1021/acs.inorgchem.0c00490. ISSN 0020-1669. PMID 32412240. S2CID 218647656.
  32. ^ a b Jia, Dingxian; Zhu, Aimei; Zhang, Yong; Deng, Jie (March 2007). "New Selenidogermanates with Transition-Metal Complexes as Counterions: Solvothermal Synthesis, Crystal Structures, and Properties of [Mn(en)3]2Ge2Se6 and [Fe(dien)2]2Ge2Se6". Monatshefte für Chemie - Chemical Monthly. 138 (3): 191–197. doi:10.1007/s00706-007-0596-3. ISSN 0026-9247. S2CID 95254867.
  33. ^ a b van Almsick, Tobias; Loose, Anja; Sheldrick, William S. (January 2005). "Solvothermal Synthesis and Structure of the [Ge2Se7]4? Anion in (enH2)[{Mn(en)2(enH)}2(?-en)](Ge2Se7)2 and [Mn(dien)2]2Ge2Se7". Zeitschrift für anorganische und allgemeine Chemie (in German). 631 (1): 21–23. doi:10.1002/zaac.200400409. ISSN 0044-2313.
  34. ^ a b Chen, Jiang-Fang; Jin, Qin-Yan; Pan, Ying-Li; Zhang, Yong; Jia, Ding-Xian (January 2010). "Solvothermal Syntheses and Characterization of New Transition Metal Chalcogenidogermanates [{Co(tepa)} 2 (μ-Ge 2 S 6 )] and [{M(tepa)} 2 (μ-Ge 2 Se 6 )] (M = Mn, Fe) (tepa = Tetraethylenepentamine)". Zeitschrift für anorganische und allgemeine Chemie. 636 (1): 230–235. doi:10.1002/zaac.200900141.
  35. ^ Haddadpour, Sima; Melullis, Maike; Staesche, Halgard; Mariappan, C. R.; Roling, Bernhard; Clérac, Rodolphe; Dehnen, Stefanie (2009-02-16). "Inorganic Frameworks from Selenidotetrelate Anions [T 2 Se 6 ] 4− (T = Ge, Sn): Synthesis, Structures, and Ionic Conductivity of [K 2 (H 2 O) 3 ][MnGe 4 Se 10 ] and (NMe 4 ) 2 [MSn 4 Se 10 ] (M = Mn, Fe)". Inorganic Chemistry. 48 (4): 1689–1698. doi:10.1021/ic802170f. ISSN 0020-1669. PMID 19159241.
  36. ^ Van Almsick, Tobias; Sheldrick, William S. (2005-11-15). "Bis(trimethylammonium) decaselenidotetragermanatomanganate(II)". Acta Crystallographica Section E: Structure Reports Online. 61 (11): m2348–m2350. doi:10.1107/S1600536805032770. ISSN 1600-5368.
  37. ^ Feng, Kai; Wang, Wendong; He, Ran; Kang, Lei; Yin, Wenlong; Lin, Zheshuai; Yao, Jiyong; Shi, Youguo; Wu, Yicheng (2013-02-18). "K 2 FeGe 3 Se 8 : A New Antiferromagnetic Iron Selenide". Inorganic Chemistry. 52 (4): 2022–2028. doi:10.1021/ic302394e. ISSN 0020-1669. PMID 23356497.
  38. ^ Zhang, Feng; Yin, Xian-Hong; Liu, Xing; Zhou, Jian (August 2011). "Two Novel Adamantane-Like Thio/Selenidogermanates with Complex Cations". Zeitschrift für anorganische und allgemeine Chemie. 637 (10): 1388–1393. doi:10.1002/zaac.201100106.
  39. ^ a b Wang, Yu-Long; Zhang, Bo; Li, Wei-An; Feng, Mei-Ling; Huang, Xiao-Ying (November 2017). "Two new 3D heterometallic chalcogenides based on copper-rich selenogermanate clusters". Inorganic Chemistry Communications. 85: 41–44. doi:10.1016/j.inoche.2017.05.023.
  40. ^ a b Liu, Hua-Wei; Wang, Kai-Yao; Ding, Dong; Sun, Meng; Cheng, Lin; Wang, Cheng (2019). "Deep eutectic solvothermal synthesis of an open framework copper selenidogermanate with pH-resistant Cs ion exchange properties". Chemical Communications. 55 (92): 13884–13887. doi:10.1039/C9CC06906B. ISSN 1359-7345. PMID 31675017. S2CID 207815079.
  41. ^ a b c Wu, Zhou; Weigend, Florian; Fenske, Dieter; Naumann, Tim; Gottfried, J. Michael; Dehnen, Stefanie (2023-02-15). "Ion-Selective Assembly of Supertetrahedral Selenido Germanate Clusters for Alkali Metal Ion Capture and Separation". Journal of the American Chemical Society. 145 (6): 3802–3811. doi:10.1021/jacs.2c13523. ISSN 0002-7863. PMC 9936546. PMID 36720465.
  42. ^ a b Jiang, Qi-Qi; Tian, Xin-Yu; Bao, A-Gula; Bao, Yongsheng; Baiyin, Menghe (August 2021). "Assembly of new quaternary TM-Cu-Ge-Se compounds (TM = Ni, Mn) by the combination of two types of metal coordination geometries". Inorganic Chemistry Communications. 130: 108683. doi:10.1016/j.inoche.2021.108683. S2CID 236383545.
  43. ^ Zhang, Yingying; Hu, Dandan; Yang, Huajun; Lin, Jian; Wu, Tao (July 2017). "Synthesis, crystal structure, near-IR photoelectric response of two 1-D selenides: [Cu 2 MSe 5 ]·[Mn(H -en) 2 (en)] (M=Ge, Sn)". Journal of Solid State Chemistry. 251: 61–64. Bibcode:2017JSSCh.251...61Z. doi:10.1016/j.jssc.2017.04.006.
  44. ^ a b Li, Guang-mao; Liu, Qiong; Wu, Kui; Yang, Zhi-hua; Pan, Shi-lie (2017). "Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses". Dalton Transactions. 46 (9): 2778–2784. doi:10.1039/C7DT00087A. ISSN 1477-9226. PMID 28165518.
  45. ^ Zhou, Molin; Li, Chao; Li, Xiaoshuang; Yao, Jiyong; Wu, Yicheng (2016). "K 2 Sn 2 ZnSe 6 , Na 2 Ge 2 ZnSe 6 , and Na 2 In 2 GeSe 6 : a new series of quaternary selenides with intriguing structural diversity and nonlinear optical properties". Dalton Transactions. 45 (18): 7627–7633. doi:10.1039/C6DT00143B. ISSN 1477-9226. PMID 27049006.
  46. ^ a b Sinagra, Charles W.; Saouma, Felix O.; Otieno, Calford O.; Lapidus, Saul H.; Zhang, Jian-Han; Craig, Andrew J.; Grima-Gallardo, Pedro; Brant, Jacilynn A.; Rosmus, Kimberly A.; Rosello, Kate E.; Jang, Joon I. (December 2021). "Synthesis, structure, linear and nonlinear optical properties of noncentrosymmetric quaternary diamond-like semiconductors, Cu2ZnGeSe4 (CZGSe) and the novel Cu4ZnGe2Se7". Journal of Alloys and Compounds. 888: 161499. doi:10.1016/j.jallcom.2021.161499. OSTI 1834616.
  47. ^ Philippidis, Aggelos; Trikalitis, Pantelis N. (October 2009). "(H2NC4H8NCH2CH2NH2)(HNCH2CH2NH2)3Zn2Ge2Se8: A new, templated one-dimensional ternary semiconductor stabilized by mixed organic cations". Polyhedron. 28 (15): 3193–3198. doi:10.1016/j.poly.2009.04.028.
  48. ^ a b Wang, Jingrui; Li, Peng; Cai, Ting; Yang, Dan-Dan; Xiong, Wei-Wei (July 2018). "Four two-dimensional ternary selenides based on group 13 and 14 metals: Syntheses, crystal structures, and electrochemical properties". Journal of Solid State Chemistry. 263: 88–93. Bibcode:2018JSSCh.263...88W. doi:10.1016/j.jssc.2018.04.018. S2CID 103292702.
  49. ^ a b Li, Xiaoshuang; Li, Chao; Gong, Pifu; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2016). "Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe 3 Se 8 , K 3 Ga 3 Ge 7 S 20 , and K 3 Ga 3 Ge 7 Se 20". Dalton Transactions. 45 (2): 532–538. doi:10.1039/C5DT03682H. ISSN 1477-9226. PMID 26599138.
  50. ^ a b c d Friedrich, Daniel; Byun, Hye Ryung; Hao, Shiqiang; Patel, Shane; Wolverton, Chris; Jang, Joon Ik; Kanatzidis, Mercouri G. (2020-10-14). "Layered and Cubic Semiconductors A Ga M ′ Q 4 ( A = K , Rb , Cs , Tl  ; M ′ 4 = Ge 4 , Sn 4  ; Q 2– = S 2– , Se 2– ) and High Third-Harmonic Generation". Journal of the American Chemical Society. 142 (41): 17730–17742. doi:10.1021/jacs.0c08638. ISSN 0002-7863. PMID 32933252. S2CID 221748402.
  51. ^ a b Li, Xiao-Hui; Suen, Nian-Tzu; Chi, Yang; Sun, Yueling; Gong, Anhua; Xue, Huaiguo; Guo, Sheng-Ping (2019-10-07). "Partial Congener Substitution Induced Centrosymmetric to Noncentrosymmetric Transformation Witnessed by K 3 Ga 3 (Ge 7– x M x )Se 20 (M = Si, Sn) and Their Nonlinear Optical Properties". Inorganic Chemistry. 58 (19): 13250–13257. doi:10.1021/acs.inorgchem.9b02113. ISSN 0020-1669. PMID 31553596. S2CID 203441685.
  52. ^ a b Klepp, Kurt O.; Fabian, Ferdinand (1999-12-01). "New Chalcogenogermanates with Adamantane Type Complex Anions: Preparation and Crystal Structures of K 4 Ge 4 S 10 ; Rb 4 Ge 4 S 10 , Rb 4 Ge 4 Se 10 , and Cs 4 Ge 4 Se 10". Zeitschrift für Naturforschung B. 54 (12): 1499–1504. doi:10.1515/znb-1999-1204. ISSN 1865-7117. S2CID 196894673.
  53. ^ a b Liu, Bin-Wen; Zhang, Min-Yi; Jiang, Xiao-Ming; Li, Shu-Fang; Zeng, Hui-Yi; Wang, Guo-Qiang; Fan, Yu-Hang; Su, Yong-Fei; Li, Chunsen; Guo, Guo-Cong; Huang, Jin-Shun (2017-11-14). "Large Second-Harmonic Generation Responses Achieved by the Dimeric [Ge 2 Se 4 (μ-Se 2 )] 4– Functional Motif in Polar Polyselenides A 4 Ge 4 Se 12 (A = Rb, Cs)". Chemistry of Materials. 29 (21): 9200–9207. doi:10.1021/acs.chemmater.7b03046. ISSN 0897-4756.
  54. ^ a b Hu, Xiao-Ning; Xiong, Lin; Wu, Li-Ming (2018-05-02). "Six New Members of the A 2 M II M IV 3 Q 8 Family and Their Structural Relationship". Crystal Growth & Design. 18 (5): 3124–3131. doi:10.1021/acs.cgd.8b00247. ISSN 1528-7483.
  55. ^ a b c d Loose, Anja; Sheldrick, William S. (1997-06-01). "Quaternary Selenidogermanates(IV) A 3 [AgGe 4 Se 10 ]·2H 2 O and A 2 [MnGe 4 Se 10 ]·3H 2 O (A = Rb, Cs) with Open Framework Structures". Zeitschrift für Naturforschung B. 52 (6): 687–692. doi:10.1515/znb-1997-0604. ISSN 1865-7117. S2CID 62785714.
  56. ^ Rothenberger, Alexander; Shafaei-Fallah, Maryam; Kanatzidis, Mercouri G. (2010-11-01). "Aluminosilicate Relatives: Chalcogenoaluminogermanates Rb 3 (AlQ 2 ) 3 (GeQ 2 ) 7 (Q = S, Se)". Inorganic Chemistry. 49 (21): 9749–9751. doi:10.1021/ic101627v. ISSN 0020-1669. PMID 20932019.
  57. ^ a b c d Menezes, Luke T.; Assoud, Abdeljalil; Zhang, Weiguo; Halasyamani, P. Shiv; Kleinke, Holger (2020-10-19). "Effect of Pb Substitution in Sr 2-x Pb x GeSe 4 on Crystal Structures and Nonlinear Optical Properties Predicted by DFT Calculations". Inorganic Chemistry. 59 (20): 15028–15035. doi:10.1021/acs.inorgchem.0c01949. ISSN 0020-1669. PMID 32986411. S2CID 222151303.
  58. ^ Pocha, R.; Tampier, M.; Hoffmann, R.-D.; Mosel, B. D.; Pöttgen, R.; Johrendt, Dirk (July 2003). "Crystal Structures and Properties of the Thiostannates Eu2SNS4 and Sr2SNS4 and the Selenogermanate γ-Sr2GeSe4". Zeitschrift für anorganische und allgemeine Chemie. 629 (78): 1379–1384. doi:10.1002/zaac.200300091.
  59. ^ a b Johrendt, Dirk; Tampier, Markus (2000-03-17). "Strontium Selenogermanate(III) and Barium Selenogermanate(II,IV): Synthesis, Crystal Structures, and Chemical Bonding". Chemistry - A European Journal. 6 (6): 994–998. doi:10.1002/(SICI)1521-3765(20000317)6:6<994::AID-CHEM994>3.0.CO;2-H. ISSN 0947-6539. PMID 10785819.
  60. ^ a b c d e Tang, Shimei; Zhou, Jian; Zou, Hua-Hong; Liu, Xing; Zhang, Li (2018-02-05). "A Series of Lanthanide Selenidogermanates: The First Coexistence of Three Types of Selenidogermanate Units in the Same Architecture". Inorganic Chemistry. 57 (3): 1242–1250. doi:10.1021/acs.inorgchem.7b02659. ISSN 0020-1669. PMID 29319302.
  61. ^ a b Tang, Shimei; Cao, Shumei; Zhou, Jian (July 2018). "A Series of Lanthanide Chalcogenidogermanates Displaying Two Types of 1-D Polymeric Chains". Journal of Cluster Science. 29 (4): 777–783. doi:10.1007/s10876-018-1402-6. ISSN 1040-7278. S2CID 103263516.
  62. ^ a b Choudhury, Amitava; Strobel, Sabine; Martin, Benjamin R.; Karst, Angela L.; Dorhout, Peter K. (2007-03-01). "Synthesis of a Family of Solids through the Building-Block Approach: A Case Study with Ag Substitution in the Ternary Na−Ge−Se System". Inorganic Chemistry. 46 (6): 2017–2027. doi:10.1021/ic061064z. ISSN 0020-1669. PMID 17302403.
  63. ^ Yao, Hua–Gang; Zhang, Ren–Chun; Ji, Shou–Hua; Ji, Min; An, Yong–Lin; Ning, Gui–Ling (November 2010). "Mineralizer effect on the synthesis of two types of one-dimensional chains silver-selenogermanate and selenostannate". Inorganic Chemistry Communications. 13 (11): 1296–1298. doi:10.1016/j.inoche.2010.07.020.
  64. ^ Al-Zahrani, H. Y. S.; Alsulami, Abdullah (April 2023). "Tailoring the structural, optical, and optoelectrical parameters of the thermally evaporated Ag2FeGeSe4 thin films". Journal of Materials Science: Materials in Electronics. 34 (10). doi:10.1007/s10854-023-10275-3. ISSN 0957-4522. S2CID 257902596.
  65. ^ Dang, Junhui; Wang, Naizheng; Yao, Jiyong; Wu, Yuandong; Lin, Zheshuai; Mei, Dajiang (2022-07-12). "AgGaGeSe4: An Infrared Nonlinear Quaternary Selenide with Good Performance". Symmetry. 14 (7): 1426. Bibcode:2022Symm...14.1426D. doi:10.3390/sym14071426. ISSN 2073-8994.
  66. ^ a b Jiang, Qi-Qi; Ling, Ling; Baiyin, Menghe (March 2020). "New quaternary selenogermanates of Rb2Ag2GeSe4 and Cs2Cu2GeSe4". Inorganic Chemistry Communications. 113: 107794. doi:10.1016/j.inoche.2020.107794. S2CID 214186737.
  67. ^ a b Qiu, Zhi-Xin; Pei, Shao-Min; Chen, Wen-Fa; Jiang, Xiao-Ming; Liu, Bin-Wen; Guo, Guo-Cong (2022). "AAg 3 Ga 8 Se 14 (A = Rb, Cs): second-harmonic generation responses realized through the parallel arrangement of AgSe 4 and GaSe 4 tetrahedrons". Dalton Transactions. 51 (29): 11048–11053. doi:10.1039/D2DT01614A. ISSN 1477-9226. PMID 35796155. S2CID 250004504.
  68. ^ McKeown Wessler, Garrett C.; Wang, Tianlin; Blum, Volker; Mitzi, David B. (2022-02-14). "Cubic Crystal Structure Formation and Optical Properties within the Ag–B II –M IV –X (B II = Sr, Pb; M IV = Si, Ge, Sn; X = S, Se) Family of Semiconductors". Inorganic Chemistry. 61 (6): 2929–2944. doi:10.1021/acs.inorgchem.1c03805. ISSN 0020-1669. OSTI 1865836. PMID 35107292. S2CID 246474677.
  69. ^ Guo, Yangwu; Li, Xiaoshuang; Feng, Kai; Li, Chao; Zhou, Molin; Wu, Yicheng; Yao, Jiyong (2018-04-04). "Li 7 Cd 4.5 Ge 4 Se 16 and Li 6.4 Cd 4.8 Sn 4 Se 16 : Strong Nonlinear Optical Response in Quaternary Diamond-Like Selenide Networks". Chemistry: An Asian Journal. 13 (7): 871–876. doi:10.1002/asia.201800090. PMID 29392886.
  70. ^ Ji, Bingheng; Wang, Fei; Wu, Kui; Zhang, Bingbing; Wang, Jian (2023-01-09). "d 6 versus d 10 , Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K 2 TGe 3 Ch 8 (T = Fe, Cd; Ch = S, Se)". Inorganic Chemistry. 62 (1): 574–582. doi:10.1021/acs.inorgchem.2c03852. ISSN 0020-1669. PMID 36574629.
  71. ^ Dou, Yunwei; Chen, Ying; Li, Zhuang; Iyer, Abishek K.; Kang, Bin; Yin, Wenlong; Yao, Jiyong; Mar, Arthur (2019-02-06). "SrCdGeS 4 and SrCdGeSe 4 : Promising Infrared Nonlinear Optical Materials with Congruent-Melting Behavior". Crystal Growth & Design. 19 (2): 1206–1214. doi:10.1021/acs.cgd.8b01649. ISSN 1528-7483. S2CID 104442440.
  72. ^ a b c Friedrich, Daniel; Hao, Shiqiang; Patel, Shane; Wolverton, Chris; Kanatzidis, Mercouri G. (2021-08-24). "Vast Structural and Polymorphic Varieties of Semiconductors AMM′Q 4 (A = K, Rb, Cs, Tl; M = Ga, In; M′ = Ge, Sn; Q = S, Se)". Chemistry of Materials. 33 (16): 6572–6583. doi:10.1021/acs.chemmater.1c02211. ISSN 0897-4756. S2CID 238682020.
  73. ^ Wu, Xiaowen; Hu, Yi; Pan, Hui; Su, Zhi (2016). "Na 9 Sb(Ge 2 Q 6 ) 2 (Q = S, Se): two new antimony( iii ) quaternary chalcogenides with ethane-like [Ge 2 Q 6 ] 6− ligands". RSC Advances. 6 (101): 99475–99481. Bibcode:2016RSCAd...699475W. doi:10.1039/C6RA22000B. ISSN 2046-2069.
  74. ^ Yu, Ching-Yi; Wang, Ming-Fang; Chung, Ming-Yang; Jang, Shyue-Ming; Huang, Jih-Chen; Lee, Chi-Shen (September 2008). "Synthesis and characterization of a new quaternary selenide Sr3GeSb2Se8". Solid State Sciences. 10 (9): 1145–1149. Bibcode:2008SSSci..10.1145Y. doi:10.1016/j.solidstatesciences.2007.12.010.
  75. ^ a b van Almsick, Tobias; Sheldrick, William S. (August 2005). "Methanolothermal Synthesis and Structures of the Quaternary Group 14 - Group 15 Cesium Selenidometalates Cs3AsGeSe5 and Cs4Ge2Se6". Zeitschrift für anorganische und allgemeine Chemie (in German). 631 (10): 1746–1748. doi:10.1002/zaac.200500136. ISSN 0044-2313.
  76. ^ a b Sheldrick, W. S.; Schaaf, B. (1994-05-01). "Darstellung und Kristallstruktur der Cäsium-Selenidogermanate(IV) Cs 4 Ge 4 Se 10 · 2CH 3 OH und Cs 4 Ge 2 Se 8 / Preparation and Crystal Structure of the Cesium Selenidogerm anates(IV) Cs 4 Ge 4 Se 10 · 2CH 3 OH and Cs 4 Ge 2 Se 8". Zeitschrift für Naturforschung B. 49 (5): 655–659. doi:10.1515/znb-1994-0515. ISSN 1865-7117. S2CID 97162430.
  77. ^ a b c Morris, Collin D.; Li, Hao; Jin, Hosub; Malliakas, Christos D.; Peters, John A.; Trikalitis, Pantelis N.; Freeman, Arthur J.; Wessels, Bruce W.; Kanatzidis, Mercouri G. (2013-08-27). "Cs 2 M II M IV 3 Q 8 (Q = S, Se, Te): An Extensive Family of Layered Semiconductors with Diverse Band Gaps". Chemistry of Materials. 25 (16): 3344–3356. doi:10.1021/cm401817r. ISSN 0897-4756.
  78. ^ Wang, Yingqi; Wang, Ruiqi; Liu, Qinglong; Lai, Xiaofang; Zhang, Xian; Chen, Haijie; Zheng, Chong; Lin, Jianhua; Huang, Fuqiang (2016). "Solvothermal synthesis, structure and physical properties of Cs[Cr(en) 2 MSe 4 ] (M = Ge, Sn) with [MSe 4 ] 4− tetrahedra as chelating ligand". Dalton Transactions. 45 (22): 9097–9102. doi:10.1039/C6DT00233A. ISSN 1477-9226. PMID 27164409.
  79. ^ Ma, Ni; Xiong, Lin; Chen, Ling; Wu, Li-Ming (December 2019). "Vibration uncoupling of germanium with different valence states lowers thermal conductivity of Cs2Ge3Ga6Se14". Science China Materials. 62 (12): 1788–1797. doi:10.1007/s40843-019-1192-y. ISSN 2095-8226. S2CID 204962439.
  80. ^ a b c d e f Huang-Fu, Shang-Xiong; Shen, Jin-Ni; Lin, Hua; Chen, Ling; Wu, Li-Ming (2015-06-26). "Supercubooctahedron (Cs 6 Cl) 2 Cs 5 [Ga 15 Ge 9 Se 48 ] Exhibiting Both Cation and Anion Exchange". Chemistry: A European Journal. 21 (27): 9809–9815. doi:10.1002/chem.201405719. PMID 25982195.
  81. ^ Wang, Ruiqi; Zhang, Xian; Huang, Fuqiang (October 2022). "[Cs6Cl][Ga5GeQ12] (Q = S, Se): two novel porous layered chalcohalides exhibiting two-band emission and ion exchange properties". Science China Chemistry. 65 (10): 1903–1910. doi:10.1007/s11426-022-1277-x. ISSN 1674-7291. S2CID 252363431.
  82. ^ Wu, Yang-Yang; Xiong, Lin; Jia, Fei; Chen, Ling (2018-04-16). "Cs 2 Ge 3 In 6 Se 14 : A Structure Transformation Driven by the Size Preference and Its Properties". Inorganic Chemistry. 57 (8): 4667–4672. doi:10.1021/acs.inorgchem.8b00400. ISSN 0020-1669. PMID 29601192.
  83. ^ a b c Melullis, Maike; Clérac, Rodolphe; Dehnen, Stefanie (2005). "Ternary Mn/Ge/Se anions from reactions of [Ba2(H2O)9][GeSe4]: Synthesis and characterization of compounds containing discrete or polymeric [Mn6Ge4Se17]6– units". Chemical Communications (48): 6008–6010. doi:10.1039/b513305j. ISSN 1359-7345. PMID 16333510.
  84. ^ a b Menezes, Luke T.; Richtik, Brooke N.; Assoud, Abdeljalil; Zeljkovic, Ivan D.; Farahi, Nader; Dolgos, Michelle; Kleinke, Holger (2023-01-09). "Ba 6 Ge 2 Se 12 and Ba 7 Ge 2 Se 17 : Two Centrosymmetric Barium Seleno-Germanates with Polyatomic Anion Disorder". Inorganic Chemistry. 62 (1): 285–294. doi:10.1021/acs.inorgchem.2c03373. ISSN 0020-1669. PMID 36572592. S2CID 255211186.
  85. ^ Liu, Peng-Fei; Li, Yan-Yan; Zheng, Yu-Jun; Yu, Ju-Song; Duan, Rui-Huan; Chen, Hong; Lin, Hua; Chen, Ling; Wu, Li-Ming (2017). "Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 2". Dalton Transactions. 46 (8): 2715–2721. doi:10.1039/C6DT04294E. ISSN 1477-9226. PMID 28174766.
  86. ^ Nian, Leyan; Huang, Junben; Wu, Kui; Su, Zhi; Yang, Zhihua; Pan, Shilie (2017). "BaCu 2 M IV Q 4 (M IV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations". RSC Advances. 7 (47): 29378–29385. Bibcode:2017RSCAd...729378N. doi:10.1039/C7RA05022D. ISSN 2046-2069.
  87. ^ Yin, Wenlong; Iyer, Abishek K.; Li, Chao; Yao, Jiyong; Mar, Arthur (June 2017). "Noncentrosymmetric chalcogenides BaZnSiSe4 and BaZnGeSe4 featuring one-dimensional structures". Journal of Alloys and Compounds. 708: 414–421. doi:10.1016/j.jallcom.2017.03.009.
  88. ^ Abudurusuli, Ailijiang; Li, Junjie; Tong, Tinghao; Yang, Zhihua; Pan, Shilie (2020-04-20). "LiBa 4 Ga 5 Q 12 (Q = S, Se): Noncentrosymmetric Metal Chalcogenides with a Cesium Chloride Topological Structure Displaying a Remarkable Laser Damage Threshold". Inorganic Chemistry. 59 (8): 5674–5682. doi:10.1021/acs.inorgchem.0c00431. ISSN 0020-1669. PMID 32248682. S2CID 214811024.
  89. ^ Yuan, Fang-Yu; Lin, Chen-Sheng; Huang, Yi-Zhi; Zhang, Hao; Zhou, An-Yi; Chai, Guo-Liang; Cheng, Wen-Dan (October 2021). "BaCdGeSe4: Synthesis, structure and nonlinear optical properties". Journal of Solid State Chemistry. 302: 122352. Bibcode:2021JSSCh.30222352Y. doi:10.1016/j.jssc.2021.122352.
  90. ^ Yuan, Fang-Yu; Huang, Yi-Zhi; Zhang, Hao; Lin, Chen-Sheng; Chai, Guo-liang; Cheng, Wen-Dan (2021-10-18). "Ba 4 GeSb 2 Se 11 : An Infrared Nonlinear Optical Crystal with a V-Shaped Se 3 2– Group Possessing a Large Contribution to the SHG Response". Inorganic Chemistry. 60 (20): 15593–15598. doi:10.1021/acs.inorgchem.1c02197. ISSN 0020-1669. PMID 34590833. S2CID 238230414.
  91. ^ a b c d e Cicirello, Gary; Wu, Kui; Zhang, Bing Bing; Wang, Jian (2021). "Applying band gap engineering to tune the linear optical and nonlinear optical properties of noncentrosymmetric chalcogenides La 4 Ge 3 Se x S 12− x ( x = 0, 2, 4, 6, 8, 10)". Inorganic Chemistry Frontiers. 8 (22): 4914–4923. doi:10.1039/D1QI00879J. ISSN 2052-1553. S2CID 239429516.
  92. ^ Martin, B. R.; Knaust, J. M.; Dorhout, P. K. (April 2005). "Crystal structure of nonasodium lanthanum(III) bis[hexaselenodigermanate], Na9La[Ge2Se6]2". Zeitschrift für Kristallographie - New Crystal Structures. 220 (1–4): 314. doi:10.1524/ncrs.2005.220.14.314. ISSN 2197-4578. S2CID 201120800.
  93. ^ Assoud, Abdeljalil; Soheilnia, Navid; Kleinke, Holger (July 2004). "Crystal and electronic structure of the red semiconductor Ba4LaSbGe3Se13 comprising the complex anion [Ge2Se7–Sb2Se4–Ge2Se7]14−". Journal of Solid State Chemistry. 177 (7): 2249–2254. Bibcode:2004JSSCh.177.2249A. doi:10.1016/j.jssc.2004.03.008.
  94. ^ Choudhury, Amitava; Polyakova, Larisa A.; Hartenbach, Ingo; Schleid, Thomas; Dorhout, Peter K. (November 2006). "Synthesis, Structures, and Properties of Layered Quaternary Chalcogenides of the General Formula ALnEQ4 (A = K, Rb; Ln = Ce, Pr, Eu; E = Si, Ge; Q = S, Se)". Zeitschrift für anorganische und allgemeine Chemie (in German). 632 (15): 2395–2401. doi:10.1002/zaac.200600226.
  95. ^ a b c d e f g Tang, Shimei; Liu, Xing; Zhou, Jian (September 2017). "A Series of Dimeric Selenidogermanates with Lanthanide Complexes of Multidentate Chelating Amines". Journal of Cluster Science. 28 (5): 2589–2600. doi:10.1007/s10876-017-1223-z. ISSN 1040-7278. S2CID 98926481.
  96. ^ Martin, Benjamin R.; Polyakova, Larisa A.; Dorhout, Peter K. (February 2006). "Synthesis and characterization of a family of two related quaternary selenides: Na8Eu2(Si2Se6)2 and Na9Sm(Ge2Se6)2". Journal of Alloys and Compounds. 408–412: 490–495. doi:10.1016/j.jallcom.2004.12.091.
  97. ^ a b Iyer, Ratnasabapathy G; Aitken, Jennifer A; Kanatzidis, Mercouri G (May 2004). "Noncentrosymmetric cubic thio- and selenogermanates: A0.5M1.75GeQ4 (A=Ag, Cu, Na; M=Pb, Eu; Q=S, Se)". Solid State Sciences. 6 (5): 451–459. Bibcode:2004SSSci...6..451I. doi:10.1016/j.solidstatesciences.2004.03.001.
  98. ^ Choudhury, Amitava; Dorhout, Peter K. (2006-07-01). "Destruction of Noncentrosymmetry through Chalcogenide Salt Inclusion". Inorganic Chemistry. 45 (14): 5245–5247. doi:10.1021/ic060294a. ISSN 0020-1669. PMID 16813377.
  99. ^ a b c Martin, Benjamin R.; Dorhout, Peter K. (2004-01-01). "Molten Flux Synthesis of an Analogous Series of Layered Alkali Samarium Selenogermanate Compounds". Inorganic Chemistry. 43 (1): 385–391. doi:10.1021/ic034724y. ISSN 0020-1669. PMID 14704091.
  100. ^ a b c Tampier, M.; Johrendt, D.; Pöttgen, R.; Kotzyba, G.; Rosenhahn, C.; Mosel, B. D. (2002-02-01). "Crystal Structures and Properties of Eu 2 GeSe 4 and Eu 2 Ge 2 Se 5". Zeitschrift für Naturforschung B. 57 (2): 133–140. doi:10.1515/znb-2002-0201. ISSN 1865-7117. S2CID 197320389.
  101. ^ a b c Tang, Weiwei; Liang, Jingjing; Jiang, Wenqing; Wu, Bing; Zhang, Yong; Jia, Dingxian (September 2011). "The First Examples of Selenidogermanate Salts with Lanthanide Complex Counter Cations: Solvothermal Syntheses and Characterizations of [{Ln(en)3}2(μ-OH)2]Ge2Se6 (Ln = Eu, Ho) and [{Ho(dien)2}2(μ-OH)2]Ge2Se6". Zeitschrift für anorganische und allgemeine Chemie. 637 (11): 1539–1544. doi:10.1002/zaac.201100167.
  102. ^ a b c d Chen, Ruihong; Tang, Weiwei; Liang, Jingjing; Jiang, Wenqing; Zhang, Yong; Jia, Dingxian (2012). "The first μ-Ge2Se8 ligand to lanthanide(iii) centers: solvothermal syntheses and characterizations of lanthanide selenidogermanate complexes with a pentadentate polyamine as a co-ligand". Dalton Transactions. 41 (40): 12439–12445. doi:10.1039/c2dt30960b. ISSN 1477-9226. PMID 22949067.
  103. ^ a b Choudhury, Amitava; Polyakova, Larisa A.; Strobel, Sabine; Dorhout, Peter K. (April 2007). "Two non-centrosymmetric cubic seleno-germanates related to CsCl-type structure: Synthesis, structure, magnetic and optical properties". Journal of Solid State Chemistry. 180 (4): 1381–1389. Bibcode:2007JSSCh.180.1381C. doi:10.1016/j.jssc.2007.02.002.
  104. ^ Evenson; Dorhout, Peter K. (2001-05-01). "Synthesis and Characterization of Four New Europium Group XIV Chalcogenides: K 2 EuTSe 5 and KEuTS 4 (T = Si, Ge)". Inorganic Chemistry. 40 (10): 2409–2414. doi:10.1021/ic001248s. ISSN 0020-1669. PMID 11327920.
  105. ^ Xing, Wenhao; Wang, Naizheng; Guo, Yangwu; Li, Zhuang; Tang, Jian; Kang, Kaijin; Yin, Wenlong; Lin, Zheshuai; Yao, Jiyong; Kang, Bin (2019). "Two rare-earth-based quaternary chalcogenides EuCdGeQ 4 (Q = S, Se) with strong second-harmonic generation". Dalton Transactions. 48 (47): 17620–17625. doi:10.1039/C9DT03755A. ISSN 1477-9226. PMID 31755500. S2CID 208229363.
  106. ^ a b Tang, Shimei; Zhou, Jian; Zou, Hua-Hong; Liu, Xing (2018-04-18). "Two new 1-D lanthanide selenidogermanates with the [Ge 2 Se 6 ] 4− anion as a bridging ligand to a lanthanide complex cation". Journal of Coordination Chemistry. 71 (8): 1093–1101. doi:10.1080/00958972.2018.1449209. ISSN 0095-8972. S2CID 103352365.
  107. ^ a b Gao, Lihua; Xu, Jingjing; Tian, Xinyu; Zhang, Bingbing; Wu, Xiaowen; Wu, Kui (2022-06-26). "AgGaSe 2 -Inspired Nonlinear Optical Materials: Tetrel Selenides of Alkali Metals and Mercury". Chemistry of Materials. 34 (13): 5991–5998. doi:10.1021/acs.chemmater.2c01011. ISSN 0897-4756. S2CID 250080020.
  108. ^ a b Guo, Yangwu; Liang, Fei; Yin, Wenlong; Li, Zhuang; Luo, Xiaoyu; Lin, Zhe-Shuai; Yao, Jiyong; Mar, Arthur; Wu, Yicheng (2019-04-23). "BaHgGeSe 4 and SrHgGeSe 4 : Two New Hg-Based Infrared Nonlinear Optical Materials". Chemistry of Materials. 31 (8): 3034–3040. doi:10.1021/acs.chemmater.9b01023. ISSN 0897-4756. S2CID 131951753.
  109. ^ Xing, Wenhao; Tang, Chunlan; Wang, Naizheng; Li, Chunxiao; Li, Zhuang; Wu, Jieyun; Lin, Zheshuai; Yao, Jiyong; Yin, Wenlong; Kang, Bin (2020-12-21). "EuHgGeSe 4 and EuHgSnS 4 : Two Quaternary Eu-Based Infrared Nonlinear Optical Materials with Strong Second-Harmonic-Generation Responses". Inorganic Chemistry. 59 (24): 18452–18460. doi:10.1021/acs.inorgchem.0c03176. ISSN 0020-1669. PMID 33256399. S2CID 227245551.
  110. ^ Babizhetskyy, Volodymyr; Levytskyy, Volodymyr; Smetana, Volodymyr; Wilk-Kozubek, Magdalena; Tsisar, Oksana; Piskach, Lyudmyla; Parasyuk, Oleg; Mudring, Anja-Verena (2020-02-25). "New cation-disordered quaternary selenides Tl 2 Ga 2 Tt Se 6 ( Tt =Ge, Sn)". Zeitschrift für Naturforschung B. 75 (1–2): 135–142. doi:10.1515/znb-2019-0169. ISSN 1865-7117. S2CID 211229264.
  111. ^ Khyzhun, O.Y.; Parasyuk, O.V.; Tsisar, O.V.; Piskach, L.V.; Myronchuk, G.L.; Levytskyy, V.O.; Babizhetskyy, V.S. (October 2017). "New quaternary thallium indium germanium selenide TlInGe 2 Se 6 : Crystal and electronic structure". Journal of Solid State Chemistry. 254: 103–108. Bibcode:2017JSSCh.254..103K. doi:10.1016/j.jssc.2017.07.014.
  112. ^ a b c Bellagra, H. K.; Kogut, Y. M.; Piskach, L. V. (February 2023). "Component Interaction in the Quasi-Ternary System PbSe–Ga2Se3–GeSe2". Journal of Phase Equilibria and Diffusion. 44 (1): 3–16. doi:10.1007/s11669-022-01017-9. ISSN 1547-7037. S2CID 254430712.
  113. ^ Assoud, Abdeljalil; Kleinke, Holger (2017-12-15). "A Polyselenide with a Novel Se 7 8– Unit: the Structure of Sr 19– x Pb x Ge 11 Se 44 with x = 5.0 and 6.4". European Journal of Inorganic Chemistry. 2017 (46): 5515–5520. doi:10.1002/ejic.201701180. ISSN 1434-1948.
  114. ^ Reshak, A. H.; Kogut, Y. M.; Fedorchuk, A. O.; Zamuruyeva, O. V.; Myronchuk, G. L.; Parasyuk, O. V.; Kamarudin, H.; Auluck, S.; Plucinski, K. J.; Bila, Jiri (2013). "Electronic and optical features of the mixed crystals Ag0.5Pb1.75Ge(S1–xSex)4". Journal of Materials Chemistry C. 1 (31): 4667. doi:10.1039/c3tc30713a. ISSN 2050-7526.
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