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Zinc chloride

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For the battery type, see Zinc–chloride battery.

Zinc chloride is an inorganic chemical compound with the formula ZnCl2·nH2O, with n ranging from 0 to 4.5, forming hydrates. Zinc chloride, anhydrous and its hydrates, are colorless or white crystalline solids, and are highly soluble in water. Five hydrates of zinc chloride are known, as well as four forms of anhydrous zinc chloride.[5]

Zinc chloride

Anhydrous
Zinc chloride hydrate
Monohydrate
Names
IUPAC name
Zinc chloride
Other names
  • Butter of zinc
  • Neutral zinc chloride (1:2)
  • Zinc bichloride (archaic)
  • Zinc(II) chloride
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard 100.028.720 Edit this at Wikidata
EC Number
  • 231-592-0
RTECS number
  • ZH1400000
UNII
UN number 2331
  • InChI=1S/2ClH.Zn/h2*1H;/q;; 2/p-2 checkY
    Key: JIAARYAFYJHUJI-UHFFFAOYSA-L checkY
  • InChI=1/2ClH.Zn/h2*1H;/q;; 2/p-2
    Key: JIAARYAFYJHUJI-NUQVWONBAB
  • Cl[Zn]Cl
Properties
ZnCl2
Molar mass 136.315 g/mol
Appearance White hygroscopic and very deliquescent crystalline solid
Odor odorless
Density 2.907 g/cm3
Melting point 290 °C (554 °F; 563 K)[1]
Boiling point 732 °C (1,350 °F; 1,005 K)[1]
432.0 g/100 g (25 °C)
615 g/100 g (100 °C)
Solubility soluble in ethanol, glycerol and acetone
Solubility in ethanol 430.0 g/100 ml
−65.0·10−6 cm3/mol
Structure
Tetrahedral, linear in the gas phase
Pharmacology
B05XA12 (WHO)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
 Oral toxicity, irritant[2]
GHS labelling:
GHS05: CorrosiveGHS07: Exclamation markGHS09: Environmental hazard
Danger
H302, H314, H410
P273, P280, P301 P330 P331, P305 P351 P338, P308 P310
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
3
0
0
Lethal dose or concentration (LD, LC):
  • 350 mg/kg (rat, oral)
  • 350 mg/kg (mouse, oral)
  • 200 mg/kg (guinea pig, oral)
  • 1100 mg/kg (rat, oral)
  • 1250 mg/kg (mouse, oral)
[4]
1260 mg/m3 (rat, 30 min)
1180 mg-min/m3[4]
NIOSH (US health exposure limits):
PEL (Permissible)
 TWA 1 mg/m3 (fume)[3]
REL (Recommended)
 TWA 1 mg/m3 ST 2 mg/m3 (fume)[3]
IDLH (Immediate danger)
 50 mg/m3 (fume)[3]
Safety data sheet (SDS) External SDS
Related compounds
Other anions
Other cations
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

All forms of zinc chloride are deliquescent and are produced by the reaction of zinc or its compounds with some form of hydrogen chloride. This compound is a Lewis acid, readily forming complexes. Zinc chloride finds wide application in textile processing, metallurgical fluxes, chemical synthesis of organic compounds, such as benzaldehyde, and processes to produce other compounds of zinc.[5]

History

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Zinc chloride has long been known but currently practiced industrial applications all evolved in the latter half of 20th century.[5]

An amorphous cement formed from aqueous zinc chloride and zinc oxide was first investigated in 1855 by Stanislas Sorel. Sorel later went on to investigate the related magnesium oxychloride cement, which bears his name.[6]

Dilute aqueous zinc chloride was used as a disinfectant under the name "Burnett's Disinfecting Fluid".[7] From 1839 Sir William Burnett promoted its use as a disinfectant as well as a wood preservative. The Royal Navy conducted trials into its use as a disinfectant in the late 1840s, including during the cholera epidemic of 1849; and at the same time experiments were conducted into its preservative properties as applicable to the shipbuilding and railway industries. Burnett had some commercial success with his eponymous fluid. Following his death however, its use was largely superseded by that of carbolic acid and other proprietary products.[8]

Structure and properties

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Unlike other metal dichlorides, zinc dichloride forms several crystalline forms (polymorphs). Four forms are known: α, β, γ, and δ. Each form features tetrahedral Zn2 centers surrounded by chloride ions.[9]

Form Crystal system Pearson symbol Space group No. a (nm) 　b (nm) c (nm) Z Density (g/cm3)
α tetragonal tI12 I42d 122 0.5398 0.5398 0.64223 4 3.00
β tetragonal tP6 P42/nmc 137 0.3696 0.3696 1.071 2 3.09
γ monoclinic mP36 P21/c 14 0.654 1.131 1.23328 12 2.98
δ orthorhombic oP12 Pna21 33 0.6125 0.6443 0.7693 4 2.98

Here a, b, and c are lattice constants, Z is the number of structure units per unit cell, and ρ is the density calculated from the structure parameters.[10][11][12]

The orthorhombic form (δ) rapidly changes to one of the other forms on exposure to the atmosphere. A possible explanation is that the OH− ions originating from the absorbed water facilitate the rearrangement.[9] Rapid cooling of molten ZnCl2 gives a glass.[13]

Molten ZnCl2 has a high viscosity at its melting point and a comparatively low electrical conductivity, which increases markedly with temperature.[14][15] As indicated by a Raman scattering study, the viscosity is explained by the presence of polymers,.[16] Neutron scattering study indicated the presence of tetrahedral ZnCl4 centers, which requires aggregation of ZnCl2 monomers as well.[17]

Hydrates

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Various hydrates of zinc chloride are known: ZnCl2(H2O)n with n = 1, 1.33, 2.5, 3, and 4.5.[18] The 1.33-hydrate, previously thought to be the hemitrihydrate, consists of trans-Zn(H2O)4Cl2 centers with the chlorine atoms connected to repeating ZnCl4 chains. The hemipentahydrate, structurally formulated [Zn(H2O)5][ZnCl4], consists of Zn(H2O)5Cl octahedrons where the chlorine atom is part of a [ZnCl4]2- tetrahedera. The trihydrate consists of distinct hexaaquozinc(II) cations and tetrachlorozincate anions; formulated [Zn(H2O)6][ZnCl4]. Finally, the heminonahydrate, structurally formulated [Zn(H2O)6][ZnCl4]·3H2O also consists of distinct hexaaquozinc(II) cations and tetrachlorozincate anions like the trihydrate but has three extra water molecules. These different hydrates can be produced by evaporation of aqueous solutions of zinc chloride at different temperatures.[19][20]

Preparation and purification

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Historically, zinc chlorides are prepared from the reaction of hydrochloric acid with zinc metal or zinc oxide. Aqueous acids cannot be used to produce anhydrous zinc chloride. According to an early procedure, a suspension of powdered zinc in diethyl ether is treated with hydrogen chloride, followed by drying[21] The overall method remains useful in industry, but without the solvent:[5]

Zn 2 HCl → ZnCl2 H2

Aqueous solutions may be readily prepared similarly by treating Zn metal, zinc carbonate, zinc oxide, and zinc sulfide with hydrochloric acid:[22]

ZnS 2 HCl 4 H2O → ZnCl2(H2O)4 H2S

Hydrates can be produced by evaporation of an aqueous solution of zinc chloride. The temperature of the evaporation determines the hydrates For example, evaporation at room temperature produces the 1.33-hydrate.[19][23] Lower evaporation temperatures produce higher hydrates.[20]

Commercial samples of zinc chloride typically contain water and products from hydrolysis as impurities. Laboratory samples may be purified by recrystallization from hot dioxane. Anhydrous samples can be purified by sublimation in a stream of hydrogen chloride gas, followed by heating the sublimate to 400 °C in a stream of dry nitrogen gas.[24] A simple method relies on treating the zinc chloride with thionyl chloride.[25]

Reactions

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Chloride complexes

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A number of salts containing the tetrachlorozincate anion, [ZnCl4]2−, are known.[14] "Caulton's reagent", V2Cl3(thf)6] [Zn2Cl6], which is used in organic chemistry, is an example of a salt containing [Zn2Cl6]2−.[26][27] The compound Cs3ZnCl5 contains tetrahedral [ZnCl4]2− and Cl− anions,[9] so, the compound is not caesium pentachlorozincate, but caesium tetrachlorozincate chloride. No compounds containing the [ZnCl6]4− ion (hexachlorozincate ion) have been characterized.[9] The compound ZnCl2·0.5HCl·H2O crystallizes from a solution of ZnCl2 in hydrochloric acid. It contains a polymeric anion (Zn2Cl−5)n with balancing monohydrated hydronium ions, H5O 2 ions.[9]

Adducts

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Crystal structure of ZnCl2(thf)2.[28]

The adduct with thf ZnCl2(thf)2 illustrates the tendency of zinc chloride to form 1:2 adducts with weak Lewis bases. Being soluble in ethers and lacking acidic protons, this complex is used in the synthesis of organozinc compounds.[29] A related 1:2 complex is ZnCl2(NH2OH)2 (zinc dichloride di(hydroxylamine)). Known as Crismer's salt, this complexes releases hydroxylamine upon heating.[30] The distinctive ability of aqueous solutions of ZnCl2 to dissolve cellulose is attributed to the formation of zinc-cellulose complexes, illustrating the stability of its adducts.[31] Cellulose also dissolves in molten ZnCl2 hydrate.[32] Overall, this behavior is consistent with Zn2 as a hard Lewis acid.

When solutions of zinc chloride are treated with ammonia, diverse ammine complexes are produced. In addition to the tetrahedral 1:2 complex ZnCl2(NH3)2.[33][34] the complex Zn(NH3)4Cl2·H2O also has been isolated. The latter contains the [Zn(NH3)6]2 ion,.[9] The species in aqueous solution have been investigated and show that [Zn(NH3)4]2 is the main species present with [Zn(NH3)3Cl] also present at lower NH3:Zn ratio.[35]

Aqueous solutions of zinc chloride

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Zinc chloride dissolves readily in water to give ZnClx(H2O)4−x species and some free chloride.[36][37][38] Aqueous solutions of ZnCl2 are acidic: a 6 M aqueous solution has a pH of 1.[18] The acidity of aqueous ZnCl2 solutions relative to solutions of other Zn2 salts (say the sulfate) is due to the formation of the tetrahedral chloro aqua complexes such as [ZnCl3(H2O)]-.[39] Most metal dichlorides for octahedral complexes, with stronger O-H bonds. The combination of hydrochloric acid and ZnCl2 gives a reagent known as "Lucas reagent". Such reagents were once used a test for primary alcohols. Similar reactions are the basis of industrial routes from methanol and ethanol respectively to methyl chloride and ethyl chloride.[40]

In alkali solution, zinc chloride converts to various zinc hydroxychlorides. These include [Zn(OH)3Cl]2−, [Zn(OH)2Cl2]2−, [Zn(OH)Cl3]2−, and the insoluble Zn5(OH)8Cl2·H2O. The latter is the mineral simonkolleite.[41] When zinc chloride hydrates are heated, HCl gas evolves and hydroxychlorides result.[42]

In aqueous solution ZnCl2, as well as other halides (bromide, iodide), behave interchangeably for the preparation of other zinc compounds. These salts give precipitates of zinc carbonate when treated with aqueous carbonate sources:[5]

ZnCl2 Na2CO3 → ZnCO3 2 NaCl

Ninhydrin reacts with amino acids and amines to form a colored compound "Ruhemann's purple" (RP). Spraying with a zinc chloride solution, which is colorless, forms a 1:1 complex RP:ZnCl(H2O)2, which is more readily detected as it fluoresces more intensely than RP.[43]

Redox

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Anhydrous zinc chloride melts and even boils without any decomposition up to 900 °C. When zinc metal is dissolved in molten ZnCl2 at 500–700 °C, a yellow diamagnetic solution is formed consisting of the Zn2 2, which has zinc in the oxidation state 1. The nature of this dizinc dication has been confirmed by Raman spectroscopy.[18] Although Zn2 2 is unusual, mercury, a heavy congener of zinc, forms a wide variety of Hg2 2 salts.

In the presence of oxygen, zinc chloride oxidizes to zinc oxide above 400 °C. Again, this observation indicates the nonoxidation of Zn2 .[44]

Zinc hydroxychloride

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Concentrated aqueous zinc chloride dissolves zinc oxide to form zinc hydroxychloride, which is obtained as colorless crystals:[45]

ZnCl2 ZnO H2O → 2 ZnCl(OH)

The same material forms when hydrated zinc chloride is heated.[46]

The ability of zinc chloride to dissolve metal oxides (MO)[47] is relevant to the utility of ZnCl2 as a flux for soldering. It dissolves passivating oxides, exposing the clean metal surface.[47]

Organic syntheses with zinc chloride

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Zinc chloride is an occasional laboratory reagent often as a Lewis acid. A dramatic example is the conversion of methanol into hexamethylbenzene using zinc chloride as the solvent and catalyst:[48]

15 CH3OH → C6(CH3)6 3 CH4 15 H2O

This kind of reactivity has been investigated for the valorization of C1 precursors.[49]

Examples of zinc chloride as a Lewis acid include the Fischer indole synthesis:[50]

 

Related Lewis-acid behavior is illustrated by a traditional preparation of the dye fluorescein from phthalic anhydride and resorcinol, which involves a Friedel-Crafts acylation.[51] This transformation has in fact been accomplished using even the hydrated ZnCl2 sample shown in the picture above. Many examples describe the use of zinc chloride in Friedel-Crafts acylation reactions.[52][53]

 

Zinc chloride also activates benzylic and allylic halides towards substitution by weak nucleophiles such as alkenes:[54]

 

In similar fashion, ZnCl2 promotes selective Na[BH3(CN)] reduction of tertiary, allylic or benzylic halides to the corresponding hydrocarbons.[24]

Zinc enolates, prepared from alkali metal enolates and ZnCl2, provide control of stereochemistry in aldol condensation reactions. This control is attributed to chelation at the zinc. In the example shown below, the threo product was favored over the erythro by a factor of 5:1 when ZnCl2.[55]

 

Organozinc precursor

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Being inexpensive and anhydrous, ZnCl2 is a widely used for the synthesis of many organozinc reagents, such as those used in the palladium catalyzed Negishi coupling with aryl halides or vinyl halides. The prominence of this reaction was highlighted by the award of the 2010 Nobel Prize in Chemistry to Ei-ichi Negishi.[56]

 

Rieke zinc, a highly reactive form of zinc metal, is generated by reduction of zinc dichloride with lithium. Rieke Zn is useful for the preparation of polythiophenes[57] and for the Reformatsky reaction.[58]

Uses

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Industrial organic chemistry

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Zinc chloride is used as a catalyst or reagent in diverse reactions conducted on an industrial scale. Benzaldehyde, 20,000 tons of which is produced annually in Western countries, is produced from inexpensive toluene by exploiting the catalytic properties of zinc dichloride. This process begins with the chlorination of toluene to give benzal chloride. In the presence of a small amount of anhydrous zinc chloride, a mixture of benzal chloride are treated continuously with water according to the following stoichiometry:[59]

C6H5CHCl2 H2O → C6H5CHO 2 HCl

Similarly zinc chloride is employed in hydrolysis of benzotrichloride, the main route to benzoyl chloride. It serves as a catalyst for the production of methylene-bis(dithiocarbamate).[5]

As a metallurgical flux

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The use of zinc chloride as a flux, sometimes in a mixture with ammonium chloride (see also Zinc ammonium chloride), involves the production of HCl and its subsequent reaction with surface oxides.

Zinc chloride forms two salts with ammonium chloride: [NH4]2[ZnCl4] and [NH4]3[ZnCl4]Cl, which decompose on heating liberating HCl, just as zinc chloride hydrate does. The action of zinc chloride/ammonium chloride fluxes, for example, in the hot-dip galvanizing process produces H2 gas and ammonia fumes.[60]

Other uses

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Relevant to its affinity for these paper and textiles, ZnCl2 is used as a fireproofing agent and in the process of making Vulcanized fibre, which is made by soaking paper in concentrated zinc chloride.[61][62] Zinc chloride is also used as a deodorizing agent and to make zinc soaps.[5]

Safety and health

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Zinc and chloride are essential for life. Zn2 is a component of several enzymes, e.g., carboxypeptidase and carbonic anhydrase. Thus, aqueous solutions of zinc chlorides are rarely problematic as an acute poison.[5] Anhydrous zinc chloride is however an aggressive Lewis acid as it can burn skin and other tissues. Ingestion of zinc chloride, often from soldering flux, requires endoscopic monitoring.[63] Another source of zinc chloride is zinc chloride smoke mixture ("HC") used in smoke grenades. Containing zinc oxide, hexachloroethane and aluminium powder release zinc chloride, carbon and aluminium oxide smoke, an effective smoke screen.[64] Such smoke screens can lead to fatalities.[65]

References

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Further reading

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  • N. N. Greenwood, A. Earnshaw, Chemistry of the Elements, 2nd ed., Butterworth-Heinemann, Oxford, UK, 1997.
  • Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton, Florida: CRC Press. ISBN 0-8493-0486-5.
  • The Merck Index, 7th edition, Merck & Co, Rahway, New Jersey, USA, 1960.
  • D. Nicholls, Complexes and First-Row Transition Elements, Macmillan Press, London, 1973.
  • J. March, Advanced Organic Chemistry, 4th ed., p. 723, Wiley, New York, 1992.
  • G. J. McGarvey, in Handbook of Reagents for Organic Synthesis, Volume 1: Reagents, Auxiliaries and Catalysts for C-C Bond Formation, (R. M. Coates, S. E. Denmark, eds.), pp. 220–3, Wiley, New York, 1999.
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