Dioxygen monofluoride is a binary inorganic compound radical of fluorine and oxygen with the chemical formula O2F.[1][2][3] The compound is stable only at low temperature. This is one of many known oxygen fluorides.[4]
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Other names
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3D model (JSmol)
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PubChem CID
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CompTox Dashboard (EPA)
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| Molar mass | 50.996 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis
edit- Thermal decomposition of dioxygen difluoride:[5]
- O2F2 → F O2F
- F F → F2
- Photolysis of F2 and O2 dilute in argon:
- F2 → 2F
- F O2 → O2F
Physical properties
editDioxygen monofluoride is a strong oxidizing agent, can be prepared in the coaxial reactor.[6]
References
edit- ^ Sen, K. D. (27 August 2011). Statistical Complexity: Applications in Electronic Structure. Springer Science & Business Media. p. 199. ISBN 978-90-481-3890-6. Retrieved 18 May 2023.
- ^ Campbell, G.M. (March 1990). "A kinetic study of the equilibrium between dioxygen monofluoride and dioxygen difluoride". Journal of Fluorine Chemistry. 46 (3): 357–366. doi:10.1016/S0022-1139(00)82921-8.
- ^ Ebsworth, E. A. V.; Connor, J. A.; Turner, J. J. (6 June 2016). The Chemistry of Oxygen: Pergamon Texts in Inorganic Chemistry. Elsevier. p. 757. ISBN 978-1-4831-3789-6. Retrieved 18 May 2023.
- ^ Spratley, Richard D.; Turner, J. J.; Pimentel, George C. (March 1966). "Dioxygen Monofluoride: Infrared Spectrum, Vibrational Potential Function, and Bonding". The Journal of Chemical Physics. 44 (5): 2063–2068. doi:10.1063/1.1726981.
- ^ Ebsworth, E. A. V.; Connor, J. A.; Turner, J. J. (6 June 2016). The Chemistry of Oxygen: Pergamon Texts in Inorganic Chemistry. Elsevier. pp. 756–757. ISBN 978-1-4831-3789-6. Retrieved 18 May 2023.
- ^ Council, National Research; Studies, Division on Earth and Life; Resources, Commission on Geosciences, Environment and; Wastes, Molten Salt Panel of the Committee on Remediation of Buried and Tank (26 February 1997). Evaluation of the U.S. Department of Energy's Alternatives for the Removal and Disposition of Molten Salt Reactor Experiment Fluoride Salts. National Academies Press. p. 104. ISBN 978-0-309-17492-3. Retrieved 18 May 2023.
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